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GENG Ting, ZHOU Yongzhang, LI Xingyuan, WANG Jun, CHEN Chuan, WANG Kunyi, HAN Ziqi. 2019: The discrimination between ore-forming and barren granites based on zircon REE compositions: Insights from big data mining. Geological Bulletin of China, 38(12): 1992-1998.
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Yanshanian magmatism is well developed and has obvious metallogenic specificity in Qinzhou-Hangzhou Bays of South China. With the development of in-situ zircon analysis technology, a huge number of zircon composition data has been accumulated in recent years. On the basis of collecting data published by previous researchers, the authors determined the ore-forming potential of rock masses by using zircon REE compositions through big data thinking method, and explored effective geochemical indicators for ore prospecting. Python language was used to program arbitrary combination of elements. A total of 4095 binary diagrams and 121485 ternary diagrams were obtained, and diagrams that could effectively distinguish zircon parent rock metallogenic types were automatically screened out. The results show that different types of ore-forming rocks have different degrees of differentiation. Geochemical indices related to Ce and Eu can be well distinguished, which may result from the oxygen fugacity and water content of magma. Additionally, it is observed that some new element association diagrams (i.e., Dy/Lu-Er/Lu, Gd/Dy-Er/Yb) can distinguish ore-forming types of rock bodies effectively, but the underlying geochemical mechanism has not been fully understood. In brief, the results of geochemical data mining in this paper can be used as the prospecting indicators, which can provide scientific basis for the study and prospecting of Yanshanian hydrothermal deposits in South China, and can also be used to actively explore the application of big data technology in mineralogy.
|
Grimes C B, Wooden J L, Cheadle M J, et al."Fingerprinting" tectono-magmatic provenance using trace elements in igneous zircon[J]. Contrib. Mineral. Petrol., 2015, 170(46):1-26. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=8a25a5ed3f86737db4c5947bc56e2f0f
|
|
赵振华, 严爽.矿物——找矿与成矿[J].岩石学报, 2019, 35(1):31-68. http://d.old.wanfangdata.com.cn/Periodical/ytgcj201505012
|
|
Blevin P L. Redox and compositional parameters for interpreting the granitoid metallogeny of eastern Australia:implications for gold-rich ore systems[J]. Resource Geology, 2004, 54:241-252. http://cn.bing.com/academic/profile?id=14f40b483c12cb0e4f82f6c4aca93b24&encoded=0&v=paper_preview&mkt=zh-cn
|
|
Li X, Chi G, Zhou Y, et al. Oxygen fugacity of Yanshanian granites in South China and implications for metallogeny[J]. Ore Geology Reviews, 2017, 88:690-701. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=28dc77d4ffaa488e323eea0fbf67ce44
|
|
Shen P, Hattori K, Pan H, et al. Oxidation condition and metal fertility of granitic magmas:zircon trace-element data from porphyry Cu deposits in the Central Asian Orogenic Belt[J]. Economic Geology, 2015, 110:1861-1878. http://cn.bing.com/academic/profile?id=f6fe3a0644a46c40571f18991dd6433b&encoded=0&v=paper_preview&mkt=zh-cn
|
|
Ballard J R, Palin J M, Campbell I H. Relative oxidation states of magmas inferred from Ce(Ⅳ)/Ce(Ⅲ) in zircon:application to porphyry copper deposits of northern Chile[J]. Contrib. Mineral. Petrol., 2002, 144(3):347-364.
|
|
Dilles J H, Kent A J R, Wooden J L, et al. Zircon compositional evidence for sulfur-degassing from ore-forming arc magmas[J]. Economic Geology, 2015, 110:241-251. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=01d5461b6497e27f7f847d3a07569570
|
|
周永章, 王俊, 左仁广, 等.地质领域机器学习、深度学习及Python语言[J].岩石学报, 2018, 34(11):3173-3178. http://www.ysxb.ac.cn/ysxb/ch/reader/view_abstract.aspx?file_no=20181102&flag=1
|
|
周永章, 陈烁, 张旗, 等.大数据与数学地球科学研究进展——大数据与数学地球科学专题代序[J].岩石学报, 2018, 34(1):256-263. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=ysxb98201802001
|
|
王金荣, 潘振杰, 张旗, 等.大陆板内玄武岩数据挖掘——成分多样性及在判别图中的表现[J].岩石学报, 2016, 32(7):1919-1933. http://d.old.wanfangdata.com.cn/Periodical/ysxb98201607001
|
|
杨婧, 王金荣, 张旗, 等.全球岛弧玄武岩数据挖掘——在玄武岩判别图上的表现及初步解释[J].地质通报, 2016, 35(12):1937-1949. http://dzhtb.cgs.cn/gbc/ch/reader/view_abstract.aspx?file_no=20161201&flag=1
|
|
Liu X L, Zhang Q, Li W C, et al. Applicability of large-ion lithophile and high field strength element basalt discrimination diagrams[J]. International Journal of Digital Earth, 2017, 11(7):752-760. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=10.1080/17538947.2017.1365959
|
|
Lu Y J, Loucks R R, Fiorentini M. Zircon Compositions as a Pathfinder for Porphyry Cu ±Mo ±Au Deposits[J]. Economic Geology, 2016, 19:329-347.
|
|
李晓峰, 易先奎, 朱和平.德兴金山金矿床成矿流体来源:小尺度构造和同位素地球化学证据[J].矿床地质, 2009, 28(1):42-52. http://d.old.wanfangdata.com.cn/Periodical/kcdz200901004
|
|
Li Z. Geochronology of Neoproterozoic syn-rift magmatism in the Yangtze Craton, South China and correlations with other continents:evidence for a mantle superplume that broke up Rodinia[J]. Precambrian Research, 2003, 122(1/4):85-109. http://cn.bing.com/academic/profile?id=f37b2e324eb8eddd96446f3e3d501681&encoded=0&v=paper_preview&mkt=zh-cn
|
|
Zhou X, Sun T, Shen W, et al. Petrogenesis of Mesozoic granitoids and volcanic rocks in South China:A response to tectonic evolution[J]. Episode, 2006, 29:26-33. http://cn.bing.com/academic/profile?id=8265c4b55de950ade7768c2a1625f1f4&encoded=0&v=paper_preview&mkt=zh-cn
|
|
Qiu J T, Yu X Q, Santosh M, et al. The Late Mesozoic tectonic evolution and magmatic history of west Zhejiang, SE China:implications for regional metallogeny[J]. International Journal of Earth Sciences, 2014, 103(3):713-735. http://cn.bing.com/academic/profile?id=6af7f92643c750951622bc56c1959602&encoded=0&v=paper_preview&mkt=zh-cn
|
|
华仁民, 陈培荣, 张文兰, 等.南岭与中生代花岗岩类有关的成矿作用及其大地构造背景[J].高校地质学报, 2005, 11(3):291-304. http://d.old.wanfangdata.com.cn/Periodical/gxdzxb200503002
|
|
毛景文, 张建东, 郭春丽.斑岩铜矿-浅成低温热液银铅锌-远接触带热液金矿矿床模型:一个新的矿床模型——以德兴地区为例[J].地球科学与环境学报, 2010, 32(1):1-14. http://d.old.wanfangdata.com.cn/Periodical/xagcxyxb201001001
|
|
张文兰, 华仁民, 王汝成, 等.赣南大吉山花岗岩成岩与钨矿成矿年龄的研究[J].地质学报, 2006, 80:956-962. http://d.old.wanfangdata.com.cn/Periodical/dizhixb200607003
|
|
Jie S X, Lei W X, Tao S, et al. Trace elements, U-Pb ages and Hf isotopes of zircons from Mesozoic granites in the western Nanling Range, South China:Implications for petrogenesis and W-Sn mineralization[J]. Lithos, 2011, 127:468-482. http://cn.bing.com/academic/profile?id=1bbdda5cdb722807cff3877a1ec08cda&encoded=0&v=paper_preview&mkt=zh-cn
|
|
Feng Z H, Wang C Z, Zhang M H, et al. Unusually dumbbellshaped Guposhan-Huashan twin granite plutons in Nanling Range of south China:Discussion on their incremental emplacement and growth mechanism[J]. ournal of Asian Earth Sciences, 2012, 48:9-23.
|
|
Huang L C, Jiang S Y. Highly fractionated S-type granites from the giant Dahutang tungsten deposit in Jiangnan Orogen, Southeast China:geochronology, petrogenesis and their relationship with Wmineralization[J]. Lithos, 2014, 202:207-226.
|
|
Mao J, Zhang J, Pirajno F, et al. Porphyry Cu-Au-Moepithermal Ag-Pb-Zn-distal hydrothermal Au deposits in the Dexing area, Jiangxi province, East China-A linked ore system[J]. Ore Geology Reviews, 2011, 43(1):203-216. https://www.researchgate.net/publication/251527962_Porphyry_Cu-Au-Mo-epithermal_Ag-Pb-Zn-distal_hydrothermal_Au_deposits_in_the_Dexing_area_Jiangxi_province_East_China-A_linked_ore_system
|
|
梁锦, 周永章, 李红中, 等.钦-杭结合带斑岩型铜矿的基本地质特征及成因分析[J].岩石学报, 2012, 28:3361-3372. http://d.old.wanfangdata.com.cn/Periodical/ysxb98201210022
|
|
Hong J S, Liang Q L, Leon B, et al. Geodynamic setting of the Zijinshan porphyry-epithermal Cu-Au-Mo-Ag ore system, SW Fujian Province, China:Constrains from the geochronology and geochemistry of the igneous rocks[J]. Ore Geology Reviews, 2013, 53:287-305. http://cn.bing.com/academic/profile?id=748aa61ce86af106fd73ea4526f66870&encoded=0&v=paper_preview&mkt=zh-cn
|
|
Lukasik S, Kowalski P A, Charytanowicz M, et al. Clustering using Flower Pollination Algorithm and Calinski-Harabasz Index[C]//Proceedings of the Evolutionary Computation, 2016.
|
|
Trail D, Waston E B, Tailby N D. The oxidation state of Hadean magmas and implications for early earth's atmosphere[J]. nature, 2011, 480:79-82. http://cn.bing.com/academic/profile?id=55f78fa37ccec499191a9f40eae3056a&encoded=0&v=paper_preview&mkt=zh-cn
|
|
Liang H Y, Sun W, Su W, et al. Porphyry copper-gold mineralization at Yulong, China, promoted by decreasing redox potential during magnetite alteration[J]. Economic Geology, 2009, 104:587-596.
|
|
Qiu J T, Yu X Q, M S, et al. Geochronology and magmatic oxygen fugacity of the Tongcun molybdenum deposit, northwest Zhejiang, SE China[J]. Miner Deposita, 2013, 48:545-556. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=66e856d30056778c64815686d10931ab
|
|
Richards J P. The oxidation state, and sulfur and Cu contents of arc magmas:implications for metallogeny[J]. Lithos, 2015, 233:27-45. http://cn.bing.com/academic/profile?id=d6ace9938c4126c1a011f15825a9f8e3&encoded=0&v=paper_preview&mkt=zh-cn
|
|
Richards J P. Postsubduction porphyry Cu-Au and epithermal Au deposits:Products of remelting of subduction-modified lithosphere[J]. Geology, 2009, 37:247-250. http://cn.bing.com/academic/profile?id=9ef8e00f52e3a033669633c7a970991c&encoded=0&v=paper_preview&mkt=zh-cn
|
|
Sun W, Huang R F, Li H, et al. Porphyry deposits and oxidized magmas[J]. Ore Geology Reviews, 2015, 65:97-131. http://d.old.wanfangdata.com.cn/NSTLQK/NSTL_QKJJ0232405025/
|
|
Sun W, Arculus R J, Kamenetsky V S, et al. Release of goldbearing fluids in convergent margin magmas prompted by magnetite crystallization[J]. nature, 2004, 431:975-978. http://cn.bing.com/academic/profile?id=764e89b5fb7f5c7efbe5aa6c1790b9f6&encoded=0&v=paper_preview&mkt=zh-cn
|
|
Liang H Y, Campbell I H, Allen C. Zircon Ce4+/Ce3+ ratios and ages for Yulong ore-bearing porphyries in eastern Tibet[J]. Miner Deposita, 2006, 41:152-159.
|
|
辛洪波, 曲晓明.西藏冈底斯斑岩铜矿带含矿岩体的相对氧化状态:来自锆石Ce(Ⅳ)/Ce(Ⅲ)比值的约束[J].矿物学报, 2008, 28:152-160. http://d.old.wanfangdata.com.cn/Periodical/kwxb200802007
|
|
Li C Y, Zhang H, Wang F Y, et al. The formation of the Dabaoshan porphyry molybdenum deposit induced by slab rollback[J]. Lithos, 2012, 150:101-110. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=27f880c3bd8b822458f3a45b3f2b5e3c
|
|
胥磊落, 毕献武, 陈佑纬, 等.云南金平铜厂斑岩铜钼矿区岩体锆石Ce4+/Ce3+比值及其对成矿的指示意义[J].矿物学报, 2012, 32:74-82. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=kwxb201201011
|
|
黄文婷, 李晶, 梁华英, 等.福建紫金山矿田罗卜岭铜钼矿化斑岩锆石LA-ICPMS U-Pb年龄及成矿岩浆高氧化特征研究[J].岩石学报, 2013, 29:283-293. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=ysxb98201301022
|
|
Hou Z, Zhang H, Pan X, et al. Porphyry (Cu-Mo-Au) deposits related to melting of thickened mafic lower crust:examples from the eastern Tethyan metallogenic domain[J]. Ore Geology Reviews, 2011, 39:21-45. doi: 10.1016-j.oregeorev.2010.09.002/
|
| BAI Tao, FAN Bingliang, XIAO Xia, ZHANG Chengjiang, FENG Dexin. 2019: The Eocene magmatism and mineralization of Xiariduo rocks in the northern Yulong porphyry copper belt, Tibet: Evidence from zircon U-Pb geochronology and geochemistry. Geological Bulletin of China, 38(2-3): 308-327. | |
| LIU Xinyu, ZHANG Qi, ZHANG Chengli. 2019: The establishment of oceanic andesites tectonic environment discrimination diagrams with big data method.. Geological Bulletin of China, 38(12): 1963-1970. | |
| YANG Jing, WANG Jinrong, ZHANG Qi, CHEN Wanfeng, PAN Zhenjie, DU Xueliang, JIAO Shoutao, WANG Shuhua. 2016: Global IAB data excavation: The performance in basalt discrimination diagrams and preliminary interpretation. Geological Bulletin of China, 35(12): 1937-1949. | |
| ZHOU Yong-zhang, ZENG Chang-yu, LI Hong-zhong, AN Yan-fei, LIANG Jin, Lü Wen-chao, YANG Zhi-jun, HE Jun-guo, SHEN Wen-jie. 2012: Geological evolution and ore-prospecting targets in southern segment of Qinzhou Bay-Hangzhou Bay juncture orogenic belt, southern China. Geological Bulletin of China, 31(2-3): 486-491. | |
| RAN Hao, ZHANG Wei-jie, LIU Zhi-bo. 2012: Geochemical characteristics and LA-ICP-MS zircon U-Pb dating of the Late Permian monzogranite in Hanggale, Alax Right Banner, Inner Mongolia. Geological Bulletin of China, 31(10): 1565-1575. | |
| YAO Wen-sheng, WANG Xue-qiu, XIE Xue-jing. 2011: A comparison of analytical techniques and data for international geochemical mapping samples. Geological Bulletin of China, 30(7): 1111-1118. | |
| WANG Xue-qiu, Λ.А. Ярчева, XU Shan-fa, CHI Qing-hua, Т.А.Волкова, Ж.Кушербаев, LIU Da-wen, NIE Lan-shi, ZHANG Bi-min, SUN Bin-bin, SHEN Wu-jun. 2007: Geochemical characteristic of Tianshan Mt in Kazakhstan and China, focused on the Eastern Tianshan Mt and Chu-Iliyskiy.. Geological Bulletin of China, 26(12): 1519-1530. | |
| ZHOU Xiao-dong, WU Ling, CAO Quan-xin. 2007: Geochemical mapping and structure of geochemical blocks-Coding system and family tree diagram computer drawing. Geological Bulletin of China, 26(7): 892-898. | |
| ZHANG Xiu-zhi, YANG Zhi-hong, MA Zhong-she, TANG Jun-hong. 2006: Geochemical background and geochemical baseline. Geological Bulletin of China, 25(5): 626-629. | |
| LI Tian-bin. 2000: The study of the relation of geochemical elements of the Ordovician carbonate rocks in Tianjingshan mountain, Ningxia. Geological Bulletin of China, 19(1). |
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