Abstract: In Hunan coral fossils occur in the Cretaceous strata except the Lower Oretaceous and the Tiaomajian Formation of the Middle Cretaceous, i. e. in the strata from the Qiziqiao Formation of the Middle Cretaceous to the Xikuangshan Formation of the Upper Cretaceous. They are particularly well developed in the Qiziqiao and Shetianqiao formations. From below upwards seven tetracoral assemblage zones may be tentatively established, i. e. 1. the Endophyllum-Stringophyllum assemblage zone （the Qiziqiao age）; 2. the Grypophyllum machenziense assemblage zone, 3. the Alaiophyllum xiangxi angense assemblage zone, 4. the Sinodisphyllum varabile assemblage zone, 5. the Hexagonaria schucherti-Disphyllum caespitosun assemblage zone, 6. the Phillipsastraea-Mictophyllum gigantum assemblage zone （the Shetianqiaoage）; 7. the Vesicamplexus daoxianense assemblage zone （the Xikuangshan age）. The sequence of the above-mentioned tetracoral assemblage zones reflects the vertical evolutionary trend of the Devonian tetracoral fossils of Hunan, and their lateral distribution is controlled by sedimentary environinents. In areas of carbonate rocks in Hunan, the determination of the boundary between the Middle and Upper Cretaceous is a long-standing controversial problem. According to the sequence of evolution of the tetracoral fossils, the author considers that it is advisable to draw the Middle and Upper Cretaceous boundary between the Endophyllum-Stringophyllum assemblage zone and the Grypophyllum machenziense assemblage zone. The Ma’anshan Formation represents pure carbonate sediments deposited in the early part of the Late Devonian in Hunan, and may be correlated with the Shetianqiao Formation. The Upper Limestone of the original Qiziqiao Formation in the Qiziqiao area of Xiangxiang county contain the Crypophyllum machenziense and Alaiophyllum xiangxiangense assemblage zones, so should represent the sediments deposited in the initial Shetianqiao time; and the author names it the Lower Limestone Member.