LA-ICP-MS zircon U-Pb dating and geochemical characteristics of the Late Jurassic monzonitic granite from Yilehuli Mountain in northern Da Hinggan Mountains and their geological implications
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摘要:
对大兴安岭北段伊勒呼里山地区二长花岗岩进行了LA-ICP-MS锆石U-Pb年龄和岩石地球化学研究,确定其形成时代、岩石成因,揭露区域大地构造环境。测年数据显示,二长花岗岩于158.1±0.7Ma前形成,为晚侏罗世早期岩浆演化事件的产物。地球化学结果显示,二长花岗岩具有高Si、富Na、K、Al,低Fe、Mg的特点,A/CNK值为0.83~1.09,属高钾钙碱性花岗岩;富集大离子亲石元素K、Rb,贫高场强元素Hf、Th;稀土元素总量较高,稀土元素配分曲线右倾,具弱的负Eu异常,为I型花岗岩。岩浆起源于下地壳玄武质成分的岩石部分熔融,为同碰撞期陆壳加厚过程的产物。研究区晚侏罗世早期二长花岗岩的形成与蒙古-鄂霍茨克缝合带闭合过程中的陆-陆碰撞环境有关,其形成时代限定了大兴安岭北段伊勒呼里山地区蒙古-鄂霍茨克洋的闭合时间应为晚侏罗世早期。
Abstract:LA-ICP-MS zircon U-Pb geochronologic study and whole-rock geochemical analysis were undertaken for the monzonitic granite in Yilehuli Mountain area in northern Da Hinggan Mountains, with the aim of constraining its formation time, petrogenesis and the regional tectonic setting. Dating data show that monzonitic granite formed at 158.1 ±0.7 Ma before the Late Jurassicearly magmatic evolution event. The geochemical studies show that the granite in the area has the characteristics of high Si, Na, K and Al and low Fe and Mg, with A/CNK being 0.83~1.09, thus belonging to high potassium calc alkaline granite; it is enriched in the large ion lithophile elements K, Rb, and depleted in high field strength elements Hf, Th; the total REE is higher, and the rare earth distribution curve is right-inclined, with weak negative Eu anomalies. According to these characteristics, the monzonitic granite should belong to type I granite. The magma originated from the rock melting of the of the basaltic components of the lower crust, being the product of the thickening process with the crust during the collision. The formation of the early Late Jurassic monzonitic granites in the study area were related to the continental-continental collision environment in the closure process of the Mongolian-Okhotsk suture zone, and the closing time of the Mongolia Okhotsk Ocean in North Da Hinggan Mountain-Yilehuli mountain area is also confined to early Late Jurassic.
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Keywords:
- early Late Jurassic /
- monzonitic granite /
- geochemistry /
- Mongol-Okhotsk Ocean /
- Yilehuli Mountain
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致谢: 感谢项目组全体成员的辛勤付出,感谢审稿专家对本文提出的宝贵意见。
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图 7 二长花岗岩Y-Sr/Y图解[36]
Figure 7. The Y-Sr/Y diagrams of monzonitic granite
图 9 二长花岗岩R1-R2图解[46]
Figure 9. The R1-R2 diagrams of monzonitic granite
表 1 晚侏罗世粗中粒二长花岗岩LA-ICP-MS锆石U-Th-Pb同位素测试结果(PM008TC136)
Table 1 LA-ICP-MS zircon U-Th-Pb isotope test results for the Late Jurassic coarse-grained monzonitic granite (PM008TC136)
分析序号 含量/10-6 同位素比值 年龄/Ma Pb U 206Pb/238U 1σ 误差/% 207Pb/235U 1σ 误差/% 207Pb/206Pb 1σ 误差/% 208Pb/232Th 1σ 误差/% 232Th/238U 1σ 误差/% 206Pb/238U 1σ 207Pb/235U 1σ 207Pb/206Pb 1σ 1 9 305 0.0250 0.0002 0.60 0.1802 0.0052 2.86 0.0523 0.0015 2.86 0.0107 0.0003 3.87 0.6025 0.0082 1.36 159 1 168 5 299 9 2 6 231 0.0247 0.0002 0.64 0.1722 0.0055 3.17 0.0506 0.0016 3.15 0.0101 0.0001 3.90 0.4525 0.0027 0.59 157 1 161 5 221 7 3 5 197 0.0247 0.0002 0.64 0.1734 0.0071 4.08 0.0509 0.0021 4.05 0.0100 0.0001 3.89 0.5423 0.0047 0.87 157 1 162 7 237 10 4 5 174 0.0249 0.0002 0.70 0.1807 0.0082 4.54 0.0526 0.0024 4.64 0.0108 0.0001 3.95 0.4835 0.0024 0.49 159 1 169 8 311 14 5 5 183 0.0253 0.0002 0.69 0.1789 0.0080 4.49 0.0512 0.0024 4.62 0.0104 0.0002 3.91 0.5120 0.0030 0.58 161 1 167 7 250 12 6 11 398 0.0248 0.0002 0.64 0.1813 0.0031 1.73 0.0531 0.0010 1.79 0.0109 0.0001 3.79 0.4836 0.0024 0.50 158 1 169 3 332 6 7 8 268 0.0246 0.0002 0.62 0.1959 0.0045 2.27 0.0577 0.0013 2.29 0.0114 0.0003 3.79 0.6412 0.0054 0.84 157 1 182 4 520 12 8 7 244 0.0248 0.0001 0.60 0.1818 0.0062 3.43 0.0531 0.0018 3.48 0.0121 0.0002 3.89 0.5067 0.0045 0.88 158 1 170 6 334 12 9 5 182 0.0246 0.0002 0.64 0.1676 0.0064 3.84 0.0493 0.0019 3.89 0.0120 0.0002 3.97 0.4130 0.0037 0.91 157 1 157 6 164 6 10 4 143 0.0248 0.0002 0.66 0.1680 0.0070 4.16 0.0492 0.0020 4.14 0.0125 0.0003 4.13 0.3555 0.0029 0.81 158 1 158 7 159 7 11 4 173 0.0248 0.0002 0.64 0.1698 0.0064 3.74 0.0496 0.0019 3.76 0.0125 0.0003 4.15 0.3130 0.0030 0.96 158 1 159 6 176 7 12 6 217 0.0245 0.0002 0.63 0.1738 0.0061 3.50 0.0514 0.0018 3.46 0.0117 0.0001 3.89 0.5304 0.0036 0.69 156 1 163 6 259 9 13 9 316 0.0246 0.0002 0.62 0.1674 0.0037 2.22 0.0494 0.0011 2.26 0.0105 0.0002 3.80 0.5200 0.0026 0.51 157 1 157 3 166 4 14 5 188 0.0252 0.0002 0.64 0.1721 0.0055 3.20 0.0496 0.0016 3.24 0.0111 0.0001 3.86 0.5063 0.0027 0.54 160 1 161 5 175 6 15 5 195 0.0247 0.0002 0.64 0.1731 0.0058 3.34 0.0509 0.0017 3.36 0.0104 0.0004 3.85 0.4986 0.0039 0.78 157 1 162 5 236 8 16 8 281 0.0248 0.0001 0.60 0.1735 0.0041 2.39 0.0508 0.0012 2.41 0.0106 0.0001 3.80 0.5892 0.0057 0.98 158 1 162 4 231 6 17 6 192 0.0249 0.0002 0.61 0.1727 0.0052 3.02 0.0502 0.0015 3.02 0.0104 0.0003 3.84 0.6996 0.0042 0.61 159 1 162 5 206 6 18 5 195 0.0247 0.0002 0.62 0.1849 0.0053 2.85 0.0543 0.0015 2.84 0.0102 0.0003 3.86 0.5170 0.0029 0.56 157 1 172 5 385 11 19 24 705 0.0246 0.0002 0.61 0.1678 0.0016 0.97 0.0495 0.0005 1.04 0.0099 0.0003 3.76 1.3388 0.0111 0.83 157 1 158 2 170 2 20 11 395 0.0249 0.0002 0.61 0.1797 0.0036 2.00 0.0524 0.0010 2.00 0.0098 0.0004 3.78 0.7296 0.0036 0.50 158 1 168 3 302 6 21 6 242 0.0247 0.0001 0.61 0.1858 0.0042 2.26 0.0545 0.0012 2.26 0.0104 0.0004 3.86 0.4001 0.0030 0.74 158 1 173 4 391 9 22 10 368 0.0255 0.0002 0.60 0.1735 0.0058 3.34 0.0493 0.0016 3.32 0.0108 0.0004 3.89 0.5218 0.0029 0.55 162 1 162 5 163 5 23 7 250 0.0249 0.0002 0.62 0.1721 0.0043 2.50 0.0502 0.0012 2.44 0.0107 0.0003 3.83 0.4810 0.0025 0.52 158 1 161 4 202 5 24 12 492 0.0254 0.0002 0.69 0.1727 0.0035 2.03 0.0493 0.0010 2.01 0.0133 0.0004 4.16 0.1184 0.0012 1.02 162 1 162 3 162 3 25 8 316 0.0245 0.0001 0.61 0.1773 0.0035 1.97 0.0524 0.0010 1.97 0.0123 0.0004 3.80 0.4234 0.0026 0.62 156 1 166 3 305 6 注:测试单位为天津地质矿产研究所测试中心 表 2 晚侏罗世二长花岗岩主量、微量和稀土元素组成及特征参数
Table 2 Analytical data and parameters of major, trace and rare earth elements for the Late Jurassic monzonitic granite
样品号 D0011a D0490 P11TC204 P20TC127 P20TC13 P20TC134 P20TC147 P20TC51 P20TC7 P22TC100 P8TC122 P8TC136 P8TC250 SiO2 74.02 70.42 74.38 68.98 74.14 69.34 69.28 66.04 74.70 69.22 66.96 67.92 72.78 TiO2 0.19 0.36 0.34 0.46 0.25 0.49 0.47 0.52 0.20 0.45 0.53 0.52 0.22 Al2O3 12.43 14.96 12.14 15.06 12.79 14.81 14.78 16.50 12.50 14.87 14.96 15.01 13.04 Fe2O3 1.60 1.00 1.55 1.76 1.04 1.91 1.85 2.34 1.31 2.17 1.92 2.31 0.61 FeO 0.60 2.41 1.70 1.65 1.44 1.88 1.54 1.63 1.34 1.86 1.78 1.64 2.26 MnO 0.03 0.04 0.03 0.04 0.02 0.04 0.04 0.04 0.04 0.08 0.05 0.04 0.15 MgO 0.43 0.97 0.20 0.90 0.41 0.88 0.84 0.91 0.49 0.64 1.24 1.07 0.40 CaO 0.51 1.76 0.66 1.49 0.54 1.68 1.61 1.62 0.63 1.35 2.83 2.62 1.17 Na2O 4.68 4.88 3.37 4.73 4.07 4.84 4.69 5.56 4.14 4.98 4.5 4.68 4.77 K2O 5.19 2.83 5.05 3.75 4.04 3.62 3.67 3.08 4.16 4.02 3.38 3.29 2.75 P2O5 0.02 0.13 0.08 0.21 0.10 0.21 0.19 0.24 0.10 0.12 0.24 0.17 0.06 烧失量 0.56 0.36 0.18 0.58 0.50 0.24 0.44 0.97 0.26 0.26 1.18 0.44 1.20 总计 100.26 100.12 99.68 99.61 99.34 99.94 99.40 99.45 99.87 100.02 99.57 99.71 99.41 σ 3.14 2.17 2.26 2.77 2.11 2.72 2.66 3.24 2.17 3.09 2.59 2.55 1.9 SI 3.44 8.02 1.68 7.04 3.73 6.70 6.67 6.73 4.28 4.68 9.67 8.24 3.71 Alk 9.87 7.71 8.42 8.48 8.11 8.46 8.36 8.64 8.30 9.00 7.88 7.97 7.52 A/CNK 0.87 1.05 0.94 0.92 1.01 0.99 1.00 1.06 1.07 1.04 0.99 1.01 0.99 K/Na 1.11 0.58 0.70 0.75 0.58 1.50 1.00 0.99 0.55 0.79 0.75 0.78 0.81 A/MF 3.13 2.09 1.88 1.84 2.61 2.48 2.60 2.90 2.17 2.19 2.02 2.21 2.12 AR 7.43 2.71 4.84 3.10 4.11 3.11 3.08 2.82 4.44 3.49 2.59 2.65 3.25 La 70.8 27.2 37.2 32.3 19.1 34.1 33.5 60.3 32.2 41.3 28.2 25.7 40.0 Ce 138 49.2 99.0 69.6 65.2 75.0 65.5 96.2 58.1 83.2 53.2 46.8 70.3 Pr 13.9 5.46 13.3 7.87 3.14 7.96 7.72 9.91 5.87 8.38 5.88 5.15 8.52 Nd 45.4 17.1 46.4 24.9 8.25 25.0 24.2 31.0 15.8 25.4 21.1 18.6 27.0 Sm 6.99 2.68 10.50 4.17 1.14 4.06 3.96 4.66 2.27 3.83 3.54 3.16 4.34 Eu 0.60 0.82 1.30 1.23 0.55 1.18 1.19 1.51 0.70 1.25 0.87 0.80 1.00 Gd 5.55 2.33 9.89 3.89 1.53 3.84 3.66 5.05 2.45 3.59 2.54 2.19 4.04 Tb 0.77 0.28 1.80 0.51 0.17 0.50 0.48 0.49 0.31 0.44 0.32 0.29 0.51 Dy 4.14 1.39 10.79 2.46 1.01 2.45 2.27 1.99 1.55 2.05 1.46 1.31 2.33 Ho 0.81 0.26 2.15 0.46 0.22 0.46 0.43 0.35 0.31 0.37 0.26 0.23 0.43 Er 2.26 0.87 6.44 1.44 0.85 1.45 1.33 1.13 1.11 1.18 0.70 0.61 1.32 Tm 0.37 0.13 0.97 0.22 0.15 0.21 0.20 0.16 0.19 0.18 0.10 0.09 0.19 Yb 2.38 0.81 5.66 1.36 1.09 1.40 1.29 0.96 1.33 1.19 0.65 0.59 1.20 Lu 0.36 0.14 0.98 0.24 0.21 0.26 0.23 0.17 0.26 0.23 0.10 0.09 0.21 Y 20.4 7.18 59.3 13.4 6.93 13.3 12.4 10.0 10.4 12.6 6.70 6.02 12.1 ∑REE 312.73 115.85 305.68 164.05 109.54 171.17 158.36 223.88 132.85 185.19 125.62 111.63 173.49 LREE/HREE 16.57 16.50 5.37 13.24 18.62 13.94 13.76 19.77 15.30 17.70 18.40 18.55 14.78 (La/Yb)N 29.75 33.58 6.57 23.75 17.52 24.36 25.97 62.81 24.21 34.71 43.38 43.56 33.33 (La/Sm)N 10.13 10.15 3.54 7.75 16.75 8.40 8.46 12.94 14.19 10.78 7.97 8.13 9.22 δCe 1.00 0.92 1.07 1.02 1.85 1.06 0.95 0.86 0.95 1.02 0.95 0.93 0.88 δEu 0.29 0.98 0.38 0.92 1.27 0.90 0.94 0.95 0.90 1.02 0.85 0.88 0.72 Sr 92.4 684 36.7 342 113 322 315 869 125 295 272 695 165 Rb 124 77.5 116 79.1 107 82.3 85.5 67.9 116 106 132 65.8 72.5 Ba 330 546 122 844 599 758 812 850 590 922 824 625 637 Th 9.13 10.3 12.7 6.92 13.3 9.02 7.88 9.62 13.7 14.0 10.3 6.86 10.9 Nb 15.1 8.25 22.9 8.73 10.5 10.0 8.64 9.33 10.9 10.1 11.8 6.96 9.95 Zr 193 125 354 189 117 201 176 172 127 216 247 142 123 Cr 44.8 11.4 6.09 7.61 4.07 6.71 5.23 7.31 5.83 4.30 52.6 25.1 6.94 Ni 5.27 8.46 7.04 6.41 3.30 5.35 4.86 4.68 4.73 3.96 7.49 5.71 5.31 Ta 0.98 0.74 1.61 1.12 0.82 1.07 0.86 1.03 0.86 1.07 0.70 0.58 0.82 Cs 1.98 4.21 3.41 2.04 2.52 3.57 4.03 2.92 2.04 4.71 1.33 0.94 3.15 Hf 3.46 3.99 9.34 5.83 3.89 6.92 6.05 5.37 4.27 6.72 3.86 3.21 4.69 Zr/Hf 55.78 31.33 37.90 32.42 30.08 29.05 29.09 32.03 29.74 32.14 63.99 44.24 26.23 Rb/Sr 1.34 0.11 3.16 0.23 0.95 0.26 0.27 0.08 0.93 0.36 0.49 0.09 0.44 注:主量元素含量单位为%,微量和稀土元素为10-6;主量元素测定由黑龙江省地质调查研究总院实验室完成;微量和稀土元素测定由沈阳地调中心实验测试中心完成 -
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