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安徽繁昌浮山钾长花岗岩成因及其构造意义——来自锆石U-Pb年龄、岩石地球化学和Hf同位素的证据

庞振山, 高浮萍, 朱晓强, 东前, 林鲁军

庞振山, 高浮萍, 朱晓强, 东前, 林鲁军. 2017: 安徽繁昌浮山钾长花岗岩成因及其构造意义——来自锆石U-Pb年龄、岩石地球化学和Hf同位素的证据. 地质通报, 36(2-3): 402-417.
引用本文: 庞振山, 高浮萍, 朱晓强, 东前, 林鲁军. 2017: 安徽繁昌浮山钾长花岗岩成因及其构造意义——来自锆石U-Pb年龄、岩石地球化学和Hf同位素的证据. 地质通报, 36(2-3): 402-417.
PANG Zhenshan, GAO Fuping, ZHU Xiaoqiang, DONG Qian, LIN Lujun. 2017: Petrogenesis and tectonic implications of the Fushan moyite in the Fanchang area,Anhui Province-Evidence from zircon U-Pb age,geochemistry and Hf isotopes. Geological Bulletin of China, 36(2-3): 402-417.
Citation: PANG Zhenshan, GAO Fuping, ZHU Xiaoqiang, DONG Qian, LIN Lujun. 2017: Petrogenesis and tectonic implications of the Fushan moyite in the Fanchang area,Anhui Province-Evidence from zircon U-Pb age,geochemistry and Hf isotopes. Geological Bulletin of China, 36(2-3): 402-417.

安徽繁昌浮山钾长花岗岩成因及其构造意义——来自锆石U-Pb年龄、岩石地球化学和Hf同位素的证据

基金项目: 

中国地质调查局项目《皖赣沿江地区壳幔相互作用与多成因矽卡岩矿床成矿机制研究》 编号:121201113069900

《安徽铜陵矿集区找矿预测》 编号:12120115034401

详细信息
    作者简介:

    庞振山(1968-),男,教授级高级工程师,矿物学、岩石学、矿床学专业。E-mail:pzs927@163.com

    通讯作者:

    高浮萍(1982-),女,博士,矿物学、岩石学、矿床学专业。E-mail:gfp2000@163.com

  • 中图分类号: P588.12+1

Petrogenesis and tectonic implications of the Fushan moyite in the Fanchang area,Anhui Province-Evidence from zircon U-Pb age,geochemistry and Hf isotopes

  • 摘要:

    安徽繁昌地区是长江中下游铜铁金多金属成矿带的重要组成部分。对繁昌浮山钾长花岗岩开展了详细的岩石学、岩石地球化学、锆石U-Pb 年代学和Lu-Hf 同位素分析,并在此基础上探讨了岩石成因及动力学背景。岩石地球化学研究表明,浮山钾长花岗岩为硅过饱和的准铝质-弱过铝质富碱富钾岩石,具有较高的Ga/Al 值、TFeO/MgO 值、Zr+Nb+Ce+Y 和稀土元素含量,显示出A 型花岗岩的地球化学特征。此外,浮山钾长花岗岩具有低(87Sr/86Sr)i、高δ18O、负εNd(t)和εHf(t)、负Eu 异常等地球化学特征。繁昌浮山钾长花岗岩LA-ICP-MS 锆石206Pb/238U 年龄为124.9±2.0Ma(n=15,MSWD=0.20),被解释为钾长花岗岩的形成年龄。与长江中下游地区A 型花岗岩带中的其他岩体为同期岩浆活动的产物,均形成于早白垩世。结合岩石学和区域地质资料,表明浮山钾长花岗岩可能是新生下地壳物质部分熔融作用形成的,形成浮山钾长花岗岩的新生下地壳可能由来源于富集地幔岩石圈的玄武质-安山质岩浆和少量结晶变质基底物质组成。根据锆石U-Pb 年龄,结合区域地质资料分析,晚侏罗世—早白垩世,长江中下游地区经历挤压向伸展构造应力场的转变,随时间推移,伸展作用逐渐增大,至125Ma 左右该区岩石圈可能达到了伸展的高峰期。

    Abstract:

    The Fanchang area is one of the important components of the Middle-Lower Yangtze Valley metallogenic belt. The Fushan moyite is one of the most representative and important granitic intrusions. In this paper, LA-ICP-MS zircon U-Pb dating, petrographic observations and geochemical and Hf isotopic analysis were carried out for the Fushan moyite in the Fanchang area, with the emphasis placed on the analysis of petrogenesis and tectonic implications of the Fushan moyite. The Fushan moyite has a clear A-type geochemical signature, e.g., it is of metaluminous to weakly peraluminous nature (A/CNK=0.91~1.11) and has high SiO2 (averagely 71.52%), total alkalis (Na2O+K2O=8.85%~9.60%), K*(K2O/Na2O=1.06~1.57), Fe*(TFeO/MgO=2.49~10.2), rare earth elements (ΣREE=278×10-6~376×10-6), Ga/Al ratio (2.90~3.31) and HFSE (Zr+Nb+Ce+Y=421.8×10-6~655.0×10-6). LAICP-MS zircon U-Pb dating yielded a concordant weighted mean 206Pb/238Pb age of 124.9±2.0Ma, which is similar to ages of other A-type granites in the Middle-Lower Yangtze Valley metallogenic belt, indicating that all A-type granites were formed in the Early Cretaceous. Zircons from this pluton yielded εHf(t) values between -5.8 and -10.0, which, together with U-Pb age,(87Sr/86Sr)I, δ18O and εNd(t) values of the Fushan moyite, suggest the importance of juvenile material in the magma source, and the juvenile material was composed of the basaltic andesitic magma from enriched mantle lithosphere and minor crystalline metamorphic basement. These data, together with other accurate dating data of intermediate-acid plutons and volcanic rocks in the Middle-Lower Yangtze Valley metallogenic belt, support the peak time of crustal extension at ~125Ma in this area.

  • 致谢: 野外工作期间,得到了华东冶金综合地质大队卜保全和刘晓明高级工程师的大力支持,以及中国科学院地质与地球物理研究所离子探针实验室和电子探针分析室实验人员的热情帮助,在此一并致谢.
  • 图  1   安徽繁昌浮山钾长花岗岩体地质略图(图a 据参考文献[4]修改;图b 据参考文献①修改)

    1—第四系;2—白垩系蝌蚪山组火山岩;3—白垩系中分村组火山岩;4—三叠系铜头尖组;5—三叠系东马鞍山组;6—三叠系南陵湖组;7—花岗斑岩;8—钾长花岗岩;9—花岗闪长岩;10—花岗斑岩脉;11—石英正长岩脉;12—正长岩脉;13—中生代花岗闪长岩类;14—中生代火山岩和次火山;15—A 型花岗岩带;16—正断层;17—平移断层;18—岩相分界线;19—采样位置;TLF—郯城-庐江断裂;YCF—常州-阳新断裂

    Figure  1.   Geological map of Fushan moyite in Fanchang area, Anhui Province

    图  2   安徽繁昌浮山钾长花岗岩典型照片

    a、b—斑状钾长花岗岩(a 为手标本,b 为正交偏光);c—似斑状钾长花岗岩(正交偏光);d—粒状花岗岩(正交偏光).Q—石英;Kf—钾长石

    Figure  2.   Photographs of representative samples from Fushan moyite in Fanchang area, Anhui Province

    图  3   繁昌地区浮山钾长花岗岩SiO2-(Na2O+K2O)图

    Figure  3.   SiO2 versus Na2O+K2O diagram of Fushan moyite in Fanchang area, Anhui Province

    图  4   繁昌地区浮山钾长花岗岩A/CNK-A/NK 图

    Figure  4.   A/CNK versus A/NK diagram of Fushan moyite in Fanchang area, Anhui Province

    图  5   A 型花岗岩判别图解(底图据参考文献[45])

    I、A、S—花岗岩类型;FG—分异花岗岩;OGT—未分异花岗岩

    Figure  5.   A-type granites discrimination diagram

    图  6   繁昌地区浮山钾长花岗岩球粒陨石标准化微量元素蛛网图(球粒陨石数据据参考文献[47])

    Figure  6.   Chondrite-normalized trace element spider diagram of Fushan moyite in Fanchang area, Anhui Province

    图  7   繁昌地区浮山钾长花岗岩球粒陨石标准化稀土元素配分模式图(球粒陨石数据据参考文献[48])

    Figure  7.   Chondrite-normalized REE patterns of Fushan moyite in Fanchang area, Anhui Province

    图  8   繁昌地区浮山钾长花岗岩中锆石的阴极发光(CL)图像

    (数字编号代表点号,实线圆为U-Pb 年龄测点,虚线圆为Hf 同位素分析点)

    Figure  8.   Representative CL images of zircon for Fushan moyite in Fanchang area

    图  9   繁昌地区浮山钾长花岗岩锆石U-Pb 谐和图

    Figure  9.   Zircon U-Pb concordia diagram of Fushan moyite in Fanchang area

    图  10   繁昌地区浮山钾长花岗岩Hf 同位素分布直方图

    Figure  10.   Histogram of zircon εHf(t) values for Fushan moyite in Fanchang area, Anhui Province

    图  11   繁昌地区浮山钾长花岗岩t-εHf(t)图解

    (崆岭群数据据参考文献[62];董岭群数据据参考文献[63];来自富集地幔的中基性岩浆岩:蝌蚪山玄武安山岩数据据参考文献[64];宁芜凹山、吉山和东山辉长-辉石闪长岩数据据参考文献[65-66])

    Figure  11.   Age versus εHf(t) diagram for the zircons from Fushan moyite in Fanchang area

    图  12   繁昌地区浮山钾长花岗岩元素协变图

    Figure  12.   Elements covariant diagram of the Fushan moyite in Fanchang area

    表  1   繁昌地区浮山钾长花岗岩主量元素分析结果

    Table  1   Major elements composition of samples from the Fushan moyite in Fanchang area, Anhui Province

    %
    样品编号 SiO2 TiO2 Al2O3 TFeO MnO MgO CaO Na2O K2O P2O5 烧失量 总量 Na2O+K2O K2O/Na2O A/CNK A/NK TFeO/MgO
    FC108 71.20 0.36 13.88 1.75 0.10 0.47 1.02 4.41 5.14 0.07 1.19 99.59 9.55 1.17 0.95 1.08 3.71
    FC109 70.39 0.36 14.40 1.81 0.10 0.46 0.86 4.14 5.31 0.10 1.67 99.60 9.45 1.28 1.02 1.15 3.90
    FC114 63.05 0.82 15.43 3.51 0.18 1.41 2.56 4.40 4.67 0.30 3.06 99.38 9.07 1.06 0.91 1.25 2.49
    FC118 69.97 0.38 14.20 1.89 0.09 0.63 1.15 4.27 5.08 0.09 1.81 99.56 9.35 1.19 0.97 1.13 2.99
    FS002a 73.03 0.26 13.79 1.35 0.08 0.25 0.64 3.86 5.42 0.03 0.82 99.53 9.28 1.40 1.03 1.13 5.40
    FS003a 73.14 0.30 13.89 1.45 0.08 0.26 0.67 3.90 5.12 0.03 0.70 99.54 9.02 1.31 1.05 1.16 5.58
    FS019b 73.22 0.27 13.60 1.34 0.11 0.37 0.11 4.18 5.38 0.03 0.45 99.06 9.56 1.29 1.05 1.07 3.62
    FS020b 73.61 0.26 13.14 1.62 0.01 0.23 0.17 3.45 5.40 0.03 1.11 99.04 8.85 1.57 1.11 1.14 7.04
    FS021b 73.55 0.27 13.42 1.42 0.06 0.28 0.24 3.55 5.40 0.03 0.86 99.07 8.95 1.52 1.11 1.15 5.08
    FS022b 73.28 0.27 12.91 2.12 0.10 0.33 0.36 4.20 5.40 0.03 0.41 99.42 9.60 1.29 0.96 1.01 6.44
    FS023b 72.24 0.28 13.51 1.22 0.14 0.12 0.68 4.05 5.42 0.03 0.50 98.20 9.47 1.34 0.98 1.08 10.20
     注:a 数据据参考文献[20];b 数据据参考文献[1]
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    表  2   繁昌地区浮山钾长花岗岩微量、稀土元素分析结果

    Table  2   Trace and rare earth elements composition of samples from the Fushan moyite in Fanchang area, Anhui Province

    10-6
    样品编号 Ba Rb Th Nb Ta Sr Nd Sm Zr Hf Y Sc V Cr Co Ni U Ga
    FC108 255 228 28.70 43.10 2.41 118 64.40 12.40 230 8.01 50.70 12.00 18.60 0.64 1.54 0.81 5.80 24.30
    FC109 403 223 27.20 35.70 2.01 119 49.40 9.13 213 7.33 39.10 8.58 18.50 0.32 1.42 0.43 6.30 22.10
    FC114 899 193 19.50 33.40 1.81 292 63.40 11.70 430 9.57 46.60 9.09 68.30 0.26 5.82 0.60 6.43 23.50
    FC118 425 216 27.70 37.90 2.11 160 60.50 11.10 220 7.32 46.90 7.38 20.50 0.35 1.83 0.48 10.50 23.80
    FS002a 116 226 25.20 37.80 2.14 50.60 51.50 9.66 356 9.63 57.00 4.59 4.52 0.89 0.38 0.77 5.50
    FS003a 98 207 24.80 40.30 2.26 49.90 63.10 11.80 362 10.40 61.60 6.18 6.80 4.00 0.78 2.60 5.07
    样品编号 La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu ∑REE LREE/HREE δEu (La/Yb)N
    FC108 85.20 158.0 18.30 64.40 12.40 1.02 11.00 1.82 9.16 1.80 5.37 0.98 5.82 0.85 376.13 9.22 0.26 10.50
    FC109 69.40 134.0 13.40 49.40 9.13 0.98 8.26 1.32 6.87 1.31 4.10 0.75 4.50 0.66 304.08 9.95 0.34 11.06
    FC114 79.00 145.0 16.60 63.40 11.70 1.93 10.80 1.59 8.41 1.62 4.84 0.85 5.03 0.72 351.49 9.38 0.52 11.27
    FC118 77.40 156.0 16.70 60.50 11.10 1.14 10.40 1.60 8.37 1.56 4.63 0.85 5.19 0.76 356.19 9.68 0.32 10.70
    FS002a 72.10 98.3 15.20 51.50 9.66 0.77 7.98 1.31 8.11 1.62 5.30 0.74 4.90 0.77 278.26 8.05 0.26 10.55
    FS003a 91.20 130.0 18.40 63.10 11.80 0.90 9.93 1.59 9.47 1.81 5.80 0.75 5.42 0.81 350.98 8.86 0.25 12.07
     注:a 数据据参考文献[20]
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    表  3   繁昌地区浮山钾长花岗岩LA-ICP-MS 锆石U-Th-Pb 同位素数据

    Table  3   LA-ICP-MS zircon U-Th-Pb analyses of samples from the Fushan moyite in Fanchang area

    点序号 含量/10-6 Th/U 同位素比值 年龄/Ma
    206Pb 207Pb 208Pb 232Th 238U 207Pb/206Pb 207Pb/235U 206Pb/238U 208Pb/232Th 207Pb/235U 206Pb/238U
    9 46.45 3.19 5.4 410 570 0.72 0.0485 0.0072 0.1324 0.018 0.0198 0.0012 0.0068 0.00080 126 16 126.30 7.6
    10 58.36 2.96 6.81 446 628 0.71 0.0486 0.0037 0.1323 0.0092 0.0198 0.00062 0.0068 0.00041 126 8.2 126.10 3.9
    13 82.66 4.29 14.03 1186 979 1.21 0.0485 0.0030 0.1300 0.0075 0.0194 0.00052 0.0056 0.00024 124 6.7 124.00 3.3
    19 42.98 2.512 5.04 368 491 0.75 0.0495 0.0035 0.1305 0.0086 0.0191 0.00058 0.0062 0.00035 125 7.7 122.10 3.7
    26 79.23 5.09 13.31 868 897 0.97 0.0490 0.0041 0.1331 0.010 0.0197 0.00071 0.0072 0.00041 127 9.3 125.70 4.5
    27 58.3 3.07 12.66 855 746 1.15 0.0485 0.0028 0.1324 0.0071 0.0198 0.00049 0.0074 0.00026 126 6.3 126.20 3.1
    28 86.33 4.53 14.05 764 913 0.84 0.0488 0.0019 0.1338 0.0048 0.0199 0.00036 0.0070 0.00020 128 4.3 126.80 2.3
    29 70.84 3.96 14.48 1063 860 1.24 0.0492 0.0024 0.1321 0.0059 0.0195 0.00042 0.0062 0.00019 126 5.3 124.20 2.7
    35 56.47 3.35 6.98 481 621 0.78 0.0489 0.0049 0.1315 0.012 0.0195 0.00083 0.0065 0.00049 126 11 124.50 5.2
    38 59.17 3.44 11.78 797 642 1.24 0.0483 0.0071 0.1358 0.018 0.0204 0.0012 0.0064 0.00061 129 16 130.00 7.9
    40 38.84 2.138 10.4 765 486 1.57 0.0484 0.0030 0.1295 0.0073 0.0194 0.00051 0.0061 0.00021 124 6.5 123.90 3.2
    41 36.15 2.2 6.3 489 393 1.24 0.0485 0.0079 0.1304 0.020 0.0195 0.0013 0.0056 0.00056 125 18 124.60 8.4
    46 18.3 0.929 3.82 306 213 1.44 0.0490 0.012 0.1323 0.029 0.0196 0.0018 0.0059 0.00073 126 26 125.10 11
    53 49.47 4.3 11.19 820 624 1.31 0.0477 0.0073 0.1263 0.018 0.0192 0.0012 0.0054 0.00048 121 16 122.70 7.7
    50 42.08 3.091 7.96 622 560 1.11 0.0487 0.0037 0.1286 0.0088 0.0192 0.00062 0.0056 0.00029 123 8.0 122.30 3.9
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    表  4   繁昌地区浮山钾长花岗岩锆石原位微区Hf 同位素分析结果

    Table  4   Hf isotope analyses of zircons from the Fushan moyite in Fanchang area

    样品编号 t/Ma 176Yb/177Hf 176Lu/177Hf 176Hf/177Hf εHf(0) εHft TDM1/Ma TDM2/Ma 176Hf/177Hf(t fLu/Hf
    1 125 0.085 0.00040 0.0029 0.000012 0.282469 0.000016 -10.70 -8.20 1165 1696 0.282463 -0.91
    9 126 0.038 0.00027 0.0014 0.000013 0.282460 0.000015 -11.04 -8.38 1131 1709 0.282457 -0.96
    10 126 0.049 0.00032 0.0017 0.000011 0.282414 0.000017 -12.67 -10.05 1209 1814 0.282409 -0.95
    13 124 0.049 0.00016 0.0017 0.000004 0.282461 0.000015 -10.98 -8.40 1139 1709 0.282457 -0.95
    19 122 0.049 0.00041 0.0018 0.000017 0.282439 0.000015 -11.79 -9.25 1174 1761 0.282435 -0.95
    22 130 0.054 0.00028 0.0020 0.000014 0.282472 0.000020 -10.61 -7.92 1133 1683 0.282467 -0.94
    26 126 0.069 0.00087 0.0024 0.000024 0.282500 0.000018 -9.61 -7.05 1102 1624 0.282495 -0.93
    27 126 0.042 0.00036 0.0015 0.000011 0.282485 0.000019 -10.15 -7.51 1099 1654 0.282481 -0.95
    28 127 0.083 0.00061 0.0028 0.000020 0.282477 0.000016 -10.42 -7.87 1151 1677 0.282471 -0.91
    29 124 0.086 0.00095 0.0030 0.000026 0.282506 0.000020 -9.40 -6.92 1112 1615 0.282499 -0.91
    35 125 0.042 0.00015 0.0016 0.000007 0.282458 0.000019 -11.09 -8.49 1139 1715 0.282455 -0.95
    38 130 0.052 0.00025 0.0019 0.000006 0.282474 0.000016 -10.53 -7.84 1126 1678 0.282470 -0.94
    40 124 0.073 0.00046 0.0025 0.000017 0.282456 0.000018 -11.17 -8.66 1171 1724 0.282450 -0.92
    41 125 0.092 0.00191 0.0032 0.000064 0.282486 0.000019 -10.10 -7.63 1148 1660 0.282479 -0.90
    46 125 0.051 0.00031 0.0019 0.000012 0.282479 0.000019 -10.35 -7.77 1119 1669 0.282475 -0.94
    50 122 0.043 0.00085 0.0016 0.000027 0.282535 0.000030 -8.38 -5.82 1031 1545 0.282531 -0.95
    53 123 0.091 0.00063 0.0032 0.000023 0.282483 0.000019 -10.23 -7.80 1154 1669 0.282475 -0.90
    54 125 0.041 0.00045 0.0015 0.000016 0.282460 0.000019 -11.02 -8.40 1134 1709 0.282457 -0.96
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出版历程
  • 收稿日期:  2015-06-30
  • 修回日期:  2015-09-14
  • 网络出版日期:  2023-08-15
  • 刊出日期:  2017-02-28

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