LA-ICP-MS zircon U-Pb ag-es of metamorphic rocks from Xiaomiao Formation in Tatuo area of eastern East Kunlun Mountains and their geological sig-nificance
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摘要:
东昆仑地区小庙岩组的形成时代长期存在争议,且缺少精确的年代学证据。以东昆仑东段塔妥地区小庙岩组变质碎屑岩为研究对象,采用LA-ICP-MS锆石U-Pb同位素定年方法,探讨其形成时代。结果显示,锆石具有较宽的年龄谱(1551~2624Ma),可划分为2624~2603Ma、2501~2290Ma、2196~2036Ma和1921~1551Ma年龄组,最后一组可进一步划分为1921~1690Ma和1641~1551Ma两个亚组。其中1921~1690Ma代表了物源区强烈的变质岩浆热事件,具有最强峰值特征(峰值年龄为1783Ma),而2501~2290Ma代表了源区一次变质事件,并有少量2196~2036Ma年龄记录,个别2600Ma的碎屑锆石暗示东昆仑地区存在新太古代的陆核。1641~1551Ma(加权平均年龄为1597Ma)代表了小庙岩组发生变质的时间,而物源区最晚变质年龄为1690Ma,从而确定小庙岩组形成于1690~1597Ma,属中元古代。对比碎屑锆石年龄频谱和东昆仑地区较老变质基底记录的构造-热事件信息,小庙岩组主要沉积物源可能来自于古元古界白沙河岩组,而东昆仑与华北在古元古代末-中元古代早期构造事件的对比揭示,在这一时期二者具有相似的构造演化特征。
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关键词:
- 东昆仑 /
- LA-ICP-MS锆石U-Pb年龄 /
- 小庙岩组 /
- 中元古代
Abstract:There has been long controversy over the formation age of the Xiaomiao Formation in the eastern part of East Kunlun oro-genic belt due to the lack of precise age. Choosing the meta-detrital rocks of Xiaomiao Formation in Tatuo area in eastern East Kun-lun orogenic belt as the study objects, the authors used LA-ICP-MS zircon U-Pb isotope geochronologic method to study the for-mation age of Xiaomiao Formation. The result shows that it has a wide age range (1551~2624Ma) which can be evidently divided in-to four groups, namely 2624~2603Ma, 2501~2290Ma, 2196~2036Ma and 1921~1551Ma, and the last group can be further divided into two subgroups of 1921~1690Ma and 1641~1551Ma. The age range 1921~1690Ma with the most intense peak value of 1783Ma represents a metamorphism and magmatism of the source region whereas the age range 2501~2290Ma represents a metamorphism of the source region. The detrital zircon also has the age range 2196~2036Ma with some detrital zircons being 2600Ma, which implies that there exists a Neoarchean basement in East Kunlun. The age range 1641~1551Ma (weighted average age equal to 1597Ma) repre-sents the metamorphism time of Xiaomiao Formation, and the latest metamorphism age of the source region is 1690Ma, which re-stricts the formation age of Xiaomiao Formation, which should belong to Mesoproterozoic. The contrast of the metasedimentary zir-con age range and metamorphosed basement tectonic-thermal event of the East Kunlun Mountains shows that the main sediments of Xiaomiao Formation were from Mesoproterozoic Baishahe Formation, and East Kunlun area and North China Craton have similar tectonic evolution processes from the end of Paleoproterozoic to the beginning of Mesoproterozoic, as shown by contrasting their tec-tonic-thermal events.
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致谢: LA-ICP-MS锆石U-Pb同位素测定得到天津地质矿产研究所同位素实验室李怀坤研究员和耿建珍博士的大力支持,主量和微量元素分析测试得到长安大学西部矿产资源与地质工程教育部重点实验室王柱命老师的帮助,野外和室内工作得到长安大学李佐臣副教授和陈有炘博士的大力帮助,评审专家提出了很好的的修改意见,在此一并表示衷心的感谢。
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图 1 东昆仑东段塔妥地区地质简图
1—第四系;2—侏罗系羊曲组;3—下三叠统洪水川组;4—下石炭统哈拉郭勒组;5—泥盆系牦牛山组;6—下古生界纳赤台岩群;7—新元古界万宝沟岩群;8—中元古界苦海岩群;9—中元古界小庙岩组;10—古元古界白沙河岩组;11—印支期正长花岗岩;12—印支期花岗闪长岩;13—海西期花岗闪长岩;14—海西期二长花岗岩;15—石炭系花岗闪长岩;16—加里东晚期石英闪长岩;17—蛇绿岩;18—断层;19—角度不整合;20—采样位置
Figure 1. Geological sketch map of the Tatuo area, east part of East Kunlun orogenic belt
图 2 塔妥地区小庙岩组实测剖面
1—细砾岩;2—钙质石英粉砂岩;3—泥质粉砂岩;4—粉砂质页岩;5—页岩;6—煤层;7—石英片岩;8—黑云石英片岩;9—斜长角闪片岩;10—黑云斜长片麻岩;11—石英岩;12—条带状石英岩;13—大理岩;14—条带状大理岩;15—蛇纹岩;16—蛇纹片岩;17—辉石岩;18—辉长岩;19—辉绿岩;20—断层破碎带;21—逆断层;22—产状;23—采样位置及样品编号;J1y—侏罗系羊曲组;S0—原生面理;S1—次生面理;Pt2x—中元古界小庙岩组
Figure 2. Measured geological section of Xiaomiao Formation in Tatuo area
表 1 东昆仑东段塔妥地区小庙岩组长石石英岩样品主量、 微量和稀土元素分析结果及相关参数
Table 1 Analytical data and relative parameters of major, trace and rare earth elements of arkose-quartzite sample from the Xiaomiao Formation in Tatuo area, eastern part of the East Kunlun orogenic belt
样品号 SiO2 TiO2 AI2O3 TFe2O3 MnO MgO CaO Na2O K2O P2O5 LOI Total XRD120/1 84.93 0.39 7.29 2.58 0.03 0.83 0.56 2.01 0.86 0.07 1.02 100.57 XRD120/3 88.69 0.23 5.92 1.28 0.02 0.65 0.27 1.58 0.71 0.03 0.68 100.06 样品号 al fin c alk si P k mg t qz CIA ICV XRD120/1 40.46 30.38 5.65 23.52 799.80 0.28 0.22 0.38 11.29 600.09 69.52 0.76 XRD120/3 45.17 25.38 3.75 25.70 1148.49 0.16 0.23 0.49 15.73 937.82 70.64 0.61 样品号 Li Sc V Cr Ni Co Cu Zn Ga Rb Sr Y XRD120/1 0.46 7.54 24.40 20.95 62.78 5.45 10.32 27.30 12.93 36.76 188.34 14.58 XRD120/3 1.35 2.98 13.29 13.54 24.14 2.19 7.80 18.84 8.26 25.77 135.95 4.69 样品号 Zr Nb Cd In Cs Ba Hf Ta Pb Bi Th U XRD120/1 394.50 10.69 0.22 0.02 0.31 335.89 6.41 0.51 7.06 0.03 8.41 2.60 XRD120/3 277.24 4.31 0.14 0.01 0.16 357.57 4.36 0.23 6.40 0.11 4.41 0.80 样品号 Zr/Hf Sr/Ba Cr/Zr La Ce Pr Nd Sm Eu Gd Tb Dy XRD120/1 61.50 0.56 0.05 33.14 69.52 5.63 31.26 5.70 0.48 5.04 0.44 2.39 XRD120/3 63.56 0.38 0.05 19.39 38.94 3.10 16.39 2.61 0.24 2.15 0.16 0.80 样品号 Ho Er Tm Yb Lu I REE LREE/HREE SEu SCe (La/Yb)N (La/Sm)N (Gd/Yb)N XRD120/1 0.47 1.37 0.20 1.38 0.23 157.24 12.65 0.27 1.12 16.17 3.66 2.94 XRD120/3 0.15 0.43 0.060 0.39 0.065 84.89 19.13 0.31 1.10 33.39 4.68 4.44 注:主量元素含量单位为%,微量和稀土元素单位为10-6;al、fm、c、alk、si、p、k、mg、t、qz均为样品的尼格里特征值。其中al=(Al2O3/∑)×100,fm=[(FeO+2Fe2O3+MgO+MnO)/∑]×100,c=(CaO/∑)×100,alk=[(NaO+K2O)/∑]×100,si=(SiO2/∑)×100,P=(P2O5/∑)×100,分别代表Al2O3、镁铁组分、CaO、全碱组分、SiO2及P2O5在所有氧化物中所占的质量百分比;k=K2O/(NaO+K2O),mg=MgO/(FeO+2Fe2O3+MgO+MnO),t=al-(alk+c),qz=SiO2-si,分别代表K2O在全碱中的比例、MgO在镁铁组分中的比例、Al2O3饱和程度及SiO2饱和程度的石英系数;∑=Al2O3+FeO+2Fe2O3+MgO+MnO+CaO+NaO+K2O+SiO2+P2O5+TiO2;CIA代表样品的化学蚀变指数,ICV代表样品成分变异指数 表 2 塔妥地区小庙岩组长石石英岩(XRD120/3)LA-ICP-MS锆石U-Th-Pb同位素测试结果
Table 2 LA-ICP-MS U-Th-Pb isotope composition of zircons from arkose-quartzite (XRD120/3) in Xiaomiao Formation of Tatuo area
点号 元素含量/10-6 207Pb/206Pb 同位素比值 年龄/Ma Pb U 1σ 207Pb/235U 1σ 206Pb/238U 1σ 207Pb/206Pb 1σ 207Pb/235U 1σ 206Pb/238U 1σ 1 24 60 0.3133 0.1452 0.0030 7.3002 0.1746 0.3635 0.0063 2290 36 2149 51 1999 35 2 58 220 0.0996 0.1077 0.0021 3.8705 0.0759 0.2608 0.0015 1761 35 1608 32 1494 8 3 36 92 0.6433 0.1151 0.0023 5.2267 0.1071 0.3299 0.0026 1881 36 1857 38 1838 15 4 24 57 0.7171 0.1274 0.0029 6.0186 0.1400 0.3426 0.0022 2063 40 1979 46 1899 12 5 84 314 0.0367 0.0986 0.0018 3.7378 0.0701 0.2750 0.0020 1598 34 1580 30 1566 12 6 131 265 0.4458 0.1551 0.0028 9.3656 0.1875 0.4373 0.0049 2403 31 2374 48 2339 26 7 81 258 0.2658 0.1089 0.0020 4.4528 0.0875 0.2965 0.0035 1781 33 1722 34 1674 20 8 64 202 0.1403 0.1177 0.0022 4.8741 0.0920 0.3005 0.0017 1921 33 1798 34 1694 10 9 48 86 0.3602 0.1747 0.0032 11.9191 0.2257 0.4950 0.0026 2603 31 2598 49 2592 14 10 155 607 0.0334 0.1036 0.0019 3.6885 0.0684 0.2582 0.0015 1690 33 1569 29 1481 9 11 67 212 0.2753 0.1041 0.0019 4.3121 0.0827 0.3005 0.0023 1698 34 1696 33 1694 13 12 83 293 0.0780 0.1009 0.0019 4.0199 0.0790 0.2887 0.0030 1641 34 1638 32 1635 17 13 39 117 0.3356 0.1087 0.0021 4.7548 0.0954 0.3173 0.0020 1778 36 1777 36 1777 11 14 32 73 0.3647 0.1501 0.0030 8.2335 0.1788 0.3973 0.0051 2347 34 2257 49 2156 28 15 19 41 0.4728 0.1553 0.0033 8.6393 0.1871 0.4040 0.0036 2405 36 2301 50 2187 20 16 155 439 0.0951 0.1340 0.0025 6.4874 0.1485 0.3492 0.0058 2151 33 2044 47 1931 32 17 207 811 0.0040 0.0962 0.0017 3.5432 0.0655 0.2674 0.0014 1551 34 1537 28 1527 8 18 119 268 0.3539 0.1540 0.0028 8.3883 0.1613 0.3950 0.0036 2391 31 2274 44 2146 19 19 39 124 0.2283 0.1284 0.0025 5.2221 0.1022 0.2954 0.0020 2076 34 1856 36 1669 11 20 50 156 0.2676 0.1085 0.0020 4.7249 0.0909 0.3161 0.0018 1774 34 1772 34 1771 10 21 107 352 0.0292 0.1097 0.0020 4.7555 0.0887 0.3146 0.0016 1795 33 1777 33 1763 9 22 126 414 0.1590 0.1079 0.0020 4.5467 0.0857 0.3057 0.0021 1765 33 1740 33 1720 12 23 125 325 0.1149 0.1522 0.0029 7.9229 0.1843 0.3755 0.0067 2371 32 2222 52 2055 37 24 178 539 0.4178 0.1100 0.0020 4.7790 0.0880 0.3156 0.0015 1799 33 1781 33 1768 9 25 97 341 0.0886 0.1054 0.0019 4.2249 0.0793 0.2908 0.0019 1721 33 1679 32 1646 11 26 21 76 0.1298 0.1165 0.0026 4.2611 0.0983 0.2652 0.0017 1904 41 1686 39 1516 10 27 30 67 0.5171 0.1644 0.0032 9.2772 0.1849 0.4092 0.0025 2501 33 2366 47 2211 14 28 196 914 0.1665 0.1689 0.0031 4.3480 0.0823 0.1870 0.0029 2547 30 1703 32 1105 17 29 67 195 0.8306 0.1101 0.0020 4.7825 0.0902 0.3148 0.0016 1801 34 1782 34 1764 9 30 75 244 0.5394 0.1047 0.0019 4.2694 0.0798 0.2955 0.0015 1710 34 1687 32 1669 8 31 214 453 0.2997 0.1576 0.0028 9.7895 0.1840 0.4503 0.0038 2430 30 2415 45 2397 20 32 66 199 0.4620 0.1111 0.0021 4.9152 0.0932 0.3210 0.0016 1817 34 1805 34 1795 9 33 126 328 0.3853 0.1255 0.0023 6.4161 0.1197 0.3708 0.0027 2036 32 2034 38 2033 15 34 41 101 1.4974 0.1131 0.0022 5.1632 0.1064 0.3308 0.0035 1851 35 1847 38 1842 20 35 178 555 0.1148 0.1149 0.0021 5.1447 0.0967 0.3248 0.0022 1878 32 1844 35 1813 13 36 45 81 0.6297 0.1769 0.0033 11.8750 0.2305 0.4869 0.0039 2624 31 2595 50 2557 20 37 64 175 1.1180 0.1092 0.0020 4.6622 0.0898 0.3097 0.0030 1787 34 1760 34 1739 17 38 91 270 0.4837 0.1143 0.0021 4.9714 0.0957 0.3154 0.0019 1870 34 1814 35 1767 10 39 121 314 0.5311 0.1375 0.0027 6.5280 0.1578 0.3420 0.0064 2196 34 2050 50 1896 35 40 158 463 0.2793 0.1120 0.0020 5.1440 0.0957 0.3333 0.0023 1832 33 1843 34 1854 13 41 392 1314 0.0509 0.1083 0.0019 4.5683 0.0865 0.3060 0.0028 1772 33 1744 33 1721 16 42 84 253 0.4787 0.1069 0.0020 4.5965 0.0876 0.3120 0.0022 1747 34 1749 33 1750 12 43 95 291 0.4831 0.1057 0.0019 4.4885 0.0838 0.3082 0.0017 1726 33 1729 32 1732 10 44 425 1112 1.1612 0.1103 0.0020 4.8829 0.0906 0.3212 0.0022 1804 33 1799 33 1796 13 45 240 752 0.3676 0.1069 0.0019 4.5298 0.0866 0.3073 0.0035 1748 33 1736 33 1727 19 46 249 985 0.5345 0.1117 0.0020 3.4848 0.0687 0.2266 0.0040 1827 33 1524 30 1317 23 -
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