LA-ICP-MS zircon age of volcanic rock of Shiling Formation in Tunxi area, south Anhui, and redetermination of its epoch
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摘要:
皖南屯溪地区位于江南新元古代造山带东段, 发育少量中生代燕山期石岭组流纹岩、凝灰岩等火山岩。因一直缺乏精确的测年数据, 以往研究者根据屯溪地区1:5万区域地质调查获得的石岭组火山岩全岩K-Ar年龄值115~139 Ma, 将其形成时代定为晚侏罗世-早白垩世。由于2004年前后国际地质年代表将侏罗纪与白垩纪界线由135 Ma提前到145 Ma, 石岭组火山岩的形成时代便由原来的晚侏罗世-早白垩世更改为早白垩世。在屯溪东面尤溪村石岭组流纹岩中首次获得精确的LAICP-MS锆石U-Pb年龄154.7±2.5Ma, 早于145Ma, 表明屯溪地区石岭组火山岩形成于晚侏罗世而不是早白垩世。这一发现对构建皖南乃至中国东南部晚中生代构造演化模型具有参考意义。
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关键词:
- LA-ICP-MS锆石U-Pb测年 /
- 晚侏罗世 /
- 石岭组火山岩 /
- 皖南屯溪地区
Abstract:The Tunxi area in south Anhui Province is located in the eastern segment of the Jiangnan Neoproterozoic Orogen and possesses some volcanic rocks of Shiling Formation like rhyolite and tuff. Based on the K-Ar age 115~139Ma by 1:50000 regional geological survey, previous studies believed that these volcanic rocks of Shiling Formation from Tunxi area were formed during Late Jurassic to Early Cretaceous. Owing to the change of the Jurassic-Cretaceous boundary from 135Ma to 145Ma(revised by International Commission on Stratigraphy), the Shiling Formation has thus changed its formation epoch from Late Jurassic-Early Cretaceous to Early Cretaceous. The authors obtained LA-ICP-MS zircon U-Pb weighted average age of 154.7±2.5Ma for the rhyolite from Youxi Village, east Tunxi(D047), south Anhui Province, implying that the volcanic rocks of Shiling Formation was formed in Late Jurassic(older than 145Ma), rather then in Eearly Cretaceous. This precise datum is valuable for a better understanding of tectonomagmatic evolution of south Anhui and even southeast China.
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致谢: 样品锆石U-Pb同位素测试过程中得到中国地质大学(武汉)胡兆初教授的帮助, 野外工作中得到安徽省地质矿产勘查局332地质队刘斌诚高级工程师、 王德恩教授级高级工程师等人的支持,在此一并致以诚挚的谢意。
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图 1 皖南屯溪地区地质简图和采样点位置图(据参考文献①修改)
a—研究区地理位置图;b—研究区大地构造位置图;c—屯溪地区地质图及D047采样位置;1—第四系;2—白垩系;3—晚侏罗世石岭组;4—中侏罗世-晚侏罗世早期地层;5—前三叠系;6—实测逆冲断层;7—采样位置
Figure 1. Geological sketch map of Tunxi area, south Anhui Province, showing sampling location
表 1 屯溪地区尤溪村(D047-6)石岭组流纹岩LA-ICP-MS锆石U-Th-Pb分析结果
Table 1 Zircon U-Th-Pb isotopic analyses of the rhyolite from Youxi Village, east Tunxi, South Anhui Province
样品测试点 元素含量/10-6 同位素比值 同位素年龄/Ma 不谐和度% Th U Pb Th/U 207pb/206pb 1σ 207Pb/235U 1σ 206Pb/238U 1σ 207Pb/206Pb 1σ 207Pb/235U 1σ 206Pb/238U 1σ 1 535 1038 37.2 0.52 0.06711 0.0063 0.21811 0.01999 0.02357 0.00048 841 200 200 17 150 3 33.33 2 367 707 18.4 0.52 0.04913 0.00171 0.16472 0.00582 0.02431 0.00045 154 49 155 5 155 3 0.00 3 358 602 15.7 0.59 0.04896 0.00191 0.16088 0.00631 0.02382 0.00045 146 57 151 6 152 3 -0.66 4 334 591 19.7 0.57 0.06911 0.0068 0.20986 0.02015 0.02202 0.00048 902 210 193 17 140 3 37.86 5 548 1199 38.1 0.46 0.05925 0.00528 0.18618 0.01618 0.02279 0.00046 576 200 173 14 145 3 19.31 6 441 917 23.7 0.48 0.04893 0.00142 0.16394 0.00495 0.02429 0.00043 144 39 154 4 155 3 -0.65 7 323 695 17.9 0.46 0.05463 0.00201 0.18213 0.00672 0.02418 0.00047 397 49 170 6 154 3 10.39 8 360 778 21.2 0.46 0.06235 0.00364 0.20646 0.01139 0.02402 0.00046 686 130 191 10 153 3 24.84 9 237 385 49.8 0.62 0.06403 0.00176 1.00559 0.02886 0.11387 0.00203 743 32 707 15 695 12 1.73 10 332 675 19.3 0.49 0.06292 0.00425 0.20725 0.01338 0.02389 0.00047 705 150 191 11 152 3 25.66 11 149 512 31.8 0.29 0.05914 0.00161 0.47107 0.01345 0.05776 0.00102 572 33 392 9 362 6 8.29 12 254 605 14.7 0.42 0.04931 0.00318 0.15783 0.01002 0.02321 0.00053 163 100 149 9 148 3 0.68 13 112 132 77.5 0.85 0.16952 0.00411 11.17794 0.29016 0.4781 0.00838 2553 22 2538 24 2519 37 1.35 14 314 398 59.3 0.79 0.06516 0.00167 1.15445 0.03143 0.12846 0.00225 780 30 779 15 779 13 0.00 15 255 344 48.1 0.74 0.06417 0.00211 1.07141 0.03588 0.12107 0.00226 747 40 739 18 737 13 0.27 16 138 186 28.5 0.74 0.0677 0.00194 1.24259 0.03698 0.13308 0.0024 859 33 820 17 805 14 1.86 17 117 297 7.4 0.40 0.04903 0.00271 0.16406 0.00899 0.02426 0.00052 149 86 154 8 155 3 -0.65 18 375 797 23.3 0.47 0.06626 0.00449 0.2166 0.01407 0.02371 0.00046 815 150 199 12 151 3 31.79 19 524 853 25.0 0.61 0.06009 0.00459 0.19674 0.01449 0.02375 0.00048 607 170 182 12 151 3 20.53 20 319 688 17.9 0.46 0.04927 0.00187 0.16684 0.0064 0.02455 0.00046 161 55 157 6 156 3 0.64 21 125 100 59.4 1.25 0.15273 0.00391 9.30338 0.252 0.44166 0.00788 2377 24 2368 25 2358 35 0.81 22 333 760 19.3 0.44 0.049 0.00194 0.1646 0.00652 0.02435 0.00048 148 56 155 6 155 3 0.00 23 57 161 72.9 0.35 0.13942 0.00352 7.9237 0.21246 0.41209 0.00726 2220 24 2222 24 2224 33 -0.18 24 147 388 9.7 0.38 0.04923 0.00213 0.16485 0.00714 0.02428 0.00048 159 65 155 6 155 3 0.00 25 128 395 10.2 0.33 0.04887 0.0021 0.17138 0.00736 0.02543 0.0005 142 64 161 6 162 3 -0.62 -