鲁西南地区土壤中有机氯农药的残留及其分布特征

    Residual of organochlorine pesticides and distribution features of soils in the southwest area of Shandong Province, China. Geological Bulletin of China

    • 摘要: 在鲁西南地区1.08×104km2的范围内以1点/36km2的采样密度采集表层土壤299件,测试六六六(HCH)、滴滴涕(DDT)等10项指标。研究这些指标的含量变化,发现区内土壤中停用20多年的六六六(HCH)、滴滴涕(DDT)仍有较高的检出率。土壤中六六六(HCH)4种异构体β-HCH含量最高, P,P′-DDE和P,P′-DDD为滴滴涕(DDT)的主要存在形式;进一步研究α-HCH/γ-HCH、β-HCH/γ-HCH和(P,P′-DDE+P,P′-DDD)/P, P′-DDT值的变化规律,得出调查区内仅滴滴涕(DDT)在局部可能存在新的污染源输入,而大部分地段六六六(HCH)、滴滴涕(DDT)农药使用时间较长,其组分已经通过物理、化学等作用发生了很大变化,污染是过去形成的。土壤环境质量评价结果表明区内土壤质量能保障农业生产、维护人体健康。

       

      Abstract: In the southwest area of Shandong Province within the range of 10800 km2, in total 299 top soil samples were collected with the density of 36km2, and 10 indices were determined such as HCH and DDT. By studying the variation of these content, the authors found the soil remains relatively high in HCH and DDT which have been banned to use for over 20 years. The β-HCH has the most high content in the four isomers of HCH which mainly exist in form of P,P-DDE and P,P-DDD; Furthermore, indicated by the changing rule of α-HCH/γ-HCH, β-HCH/γ-HCH and(P,P′-DDE+P,P′-DDD)/P,P′-DDT, the authors induced that locally there may exist new pollutant sources input only for HCH within surveyed area, For most area, HCH and DDT were stopped from using for a long time, their compositions had undergone huge change through physical and chemical action, so the pollutant was formed in the past. The result of soil environment quality evaluation indicates that the soil quality can guarantee agricultural production and people′s health.

       

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