山东省胶东半岛新立金矿床成因

    Genesis of Xinli gold deposit in Jiaodong Peninsula, Shandong Province

    • 摘要: 胶东半岛西北部三山岛-仓上断裂带的新立金矿床是典型的蚀变岩型金矿床。对新立金矿床的矿床地质特征和流体包裹体特征开展研究, 分析了新立金矿床的成矿流体特征, 明确新立金矿床的成因。矿床的矿化阶段划分为Ⅰ黄铁绢英岩阶段、Ⅱ石英-黄铁矿阶段、Ⅲ石英-多金属硫化物阶段和Ⅳ石英-碳酸盐阶段。将新立金矿床中的流体包裹体划分为单相液相包裹体(Ⅰ-l型)、单相气相包裹体(Ⅰ-g型)、两相富液相包裹体(Ⅱ-l型, V/V+L < 50%)、两相富气相包裹体(Ⅱ-g型, V/V+L>50%)和CO2-H2O三相包裹体(Ⅲ型, VCO2+LCO2+LH2O)。阶段Ⅰ中发育Ⅰ-l、Ⅰ-g、Ⅱ-l、Ⅱ-g和Ⅲ型流体包裹体, 均一温度为201~378℃, 盐度变化为3.06%~13.83%NaCl.eqv.; 阶段Ⅱ中发育Ⅰ-l、Ⅱ-l、Ⅱ-g和Ⅲ型流体包裹体, 均一温度为144~355℃, 盐度变化为2.07%~13.45%NaCl.eqv.; 阶段Ⅲ中发育Ⅰ-l、Ⅱ-l、Ⅱ-g和Ⅲ型流体包裹体, 均一温度为108~299℃, 盐度变化为0.35%~11.61%NaCl.eqv.; 阶段Ⅳ中发育Ⅱ-l、Ⅱ-g和Ⅲ型流体包裹体, 均一温度为102~236℃, 盐度变化为0.35%~10.49%NaCl.eqv.。激光拉曼光谱分析表明, 流体包裹体的成分为CO2、H2O和少量的CH4, 成矿流体为中-低温、低盐度的NaCl-CO2-H2O±CH4流体体系。新立金矿床阶段Ⅰ中δ18OSMOW为4.86‰~6.04‰, δDSMOW为-72.49‰~-69.27‰, 表明成矿流体主要来自岩浆水。黄铁矿中δ34SCDT为10.8‰~13.2‰, 方铅矿中δ34SCDT为7.7‰, 新立金矿床的成矿物质硫元素可能直接来源于郭家岭花岗岩。成矿过程中随着成矿流体温度的降低, 成矿流体与围岩发生反应及流体的不混溶作用使流体发生相分离作用导致金的沉淀, 成因类型是与岩浆热液有关的脉状金矿床。

       

      Abstract: The Xinli gold deposit in the Sanshandao-Cangshang fault zone in the northwest Jiaodong Peninsula is a typical altered-rock type gold deposit.This paper studies the geological characteristics and fluid inclusion characteristics of Xinli gold deposit, analyzes the ore-forming fluid characteristics of Xinli gold deposit, and defines the genesis of Xinli gold deposit.The hydrothermal mineralization period of Xinli gold deposit can be divided into Ⅰ beresitization stage, Ⅱ quartz-pyrite stage, Ⅲ quartz-polymetallic sulfide stage and Ⅳ quartz-calcite stage.The fluid inclusions in Xinli gold deposit can be divided into single-phase liquid inclusions(Ⅰ-l type), single-phase gas inclusions(Ⅰ-g type), two-phase liquid rich inclusions(Ⅱ-l type, V/V+L < 50%), two-phase gas rich inclusions(Ⅱ-g type, V/V+L>50%)and CO2-H2O three-phase inclusions(Ⅲ type, VCO2+LCO2+ LH2O).In stage I, type Ⅰ-l, Ⅰ-g, Ⅱ-l, Ⅱ-g and Ⅲ fluid inclusions are developed, with homogenization temperature ranging from 201℃ to 378℃, and the salinity ranging from 3.06%NaCl.eqv. to 13.83% NaCl.eqv.. In stage Ⅱ, type Ⅰ-l, Ⅱ-l, Ⅱ-g and Ⅲ fluid inclusions are developed, with homogenization temperature ranging from 144℃ to 355℃, and the salinity ranging from 2.07%NaCl.eqv. to 13.45% NaCl.eqv.; In stage Ⅲ, type Ⅰ-l, Ⅱ-l, Ⅱ-g and Ⅲ fluid inclusions are developed, with homogenization temperature ranging from 108℃ to 299℃, and the salinity ranging from 0.35%NaCl.eqv. to 11.61% NaCl.eqv.; In stage Ⅳ, type Ⅱ-l, Ⅱ-g and Ⅲ fluid inclusions are developed, with homogenization temperature ranging from 102℃ to 236℃, and the salinity ranging from 0.35%NaCl.eqv. to 10.49% NaCl.eqv.Laser Raman spectroscopy shows that the fluid inclusions are composed of CO2, H2O and a small amount of CH4.The ore-forming fluid is a medium-low temperature and low salinity NaCl-CO2-H2O±CH4 fluid system.In the stage Ⅰ of Xinli gold deposit, δ18Owater SMOW=4.86‰~6.04‰, δDSMOW=-72.49‰~-69.27‰, indicating that ore-forming fluids mainly come from magmatic water.The δ34SCDT values of pyrite range from 10.8‰ to 13.2‰, and the δ34SCDT values of galena is 7.7‰.The sulfur element of xinli gold deposit may be directly derived from Guojialing granite.With the decrease of ore-forming fluid temperature, the ore-forming fluid reacts with the surrounding rock and the immiscibility of the fluid leads to the phase separation of the fluid, which leads to the precipitation of gold.The genetic type is vein gold deposit related to magmatic hydrothermal solution.

       

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