川南煤田古叙矿区龙潭组煤中稀土元素及其开发潜力

    Rare earth elements and its development potential in the Longtan Formation coal of the Guxu mining area, South Sichuan coalfield

    • 摘要:
      研究目的 稀土元素是良好的地球化学指示剂,且工业利用潜力巨大。古叙矿区是四川省的主要产煤基地,其稀土元素对于指示煤系地层物源、反映沉积环境等具有重要的研究价值。
      研究方法 利用电感耦合等离子质谱仪(ICP-MS)测定了上二叠统龙潭组煤层样品的稀土元素含量,并运用稀土元素地球化学参数分析其地球化学特征。
      研究结果 稀土元素富集系数及其经济价值评价图显示,古叙矿区上二叠统龙潭组煤中稀土元素含量为485×10−6~1629×10−6,平均863×10−6,属于富集等级;C23、C24、C25三个煤层具有开发前景。
      结论 稀土元素标准化分布模式及其δCe、δEu、YN/HoN等地球化学参数指示,龙潭组煤系沉积物源区主要来自康滇古陆的峨眉山玄武岩风化壳,∑REY−(La/Yb)N判别图解和负Eu异常特征表明,泥炭沼泽也受到酸性岩碎屑输入的影响。海陆交互过程使来自峨眉山玄武岩风化壳的碎屑物质进一步遭受风化,海水的影响也促进了稀土元素的富集。火山灰的输入导致古叙矿区龙潭组煤系稀土元素Y出现正异常,并对稀土元素富集起到一定作用。

       

      Abstract:
      Objective Rare earth elements (REEs) are recognized as effective geochemical indicators and possess significant potential for industrial utilization. The Guxu mining area, a major coal−producing base in Sichuan Province, holds substantial research value in terms of elucidating the provenance of coal−bearing strata and reflecting sedimentary environments through REE studies.
      Methods Seven coal samples from the C13, C14, C16, C17, C23, C24, and C25 coal seams of the Upper Permian Longtan Formation were collected. Inductively Coupled Plasma Mass Spectrometry (ICP−MS) was employed to determine REE concentrations. Geochemical parameters of REEs were applied to analyze the geochemical characteristics of the coal from the Longtan Formation.
      Results The enrichment coefficients of REEs and their economic evaluation diagram revealed that the total REE content in the coal of the Longtan Formation ranges from 485×10−6 to 1629×10−6 (average: 863×10−6), classified as an enrichment grade. The C23, C24, and C25 coal seams fall within the prospective range for exploitation.
      Conclusions The standardized REE distribution patterns and geochemical parameters (δCe, δEu, YN/HoN) indicate that the sedimentary provenance of the Longtan Formation coal−bearing strata was primarily derived from the weathering crust of the Mount Emei basalt in the Kangdian Oldland. The ∑REY–(La/Yb)N discriminant diagram and negative Eu anomaly suggest that the peat swamp was also influenced by inputs of acidic rock debris. During marine−terrestrial transitional processes, clastic materials from the Mount Emei basalt weathering crust underwent further weathering, while seawater interactions promoted REE enrichment. The input of volcanic ash has led to the positive yttrium anomaly in the coal measures of the Longtan Formation in the Guxu mining area and contributed to the enrichment of rare earth elements.

       

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