川西南雷波安寨坪地区萤石矿成因分析:稀土元素地球化学及流体包裹体的制约

    Genetic analysis of the Anzhaiping fluorite deposit in Leibo, Southwestern Sichuan: Constraints from rare earth element geochemistry and fluid inclusions

    • 摘要:
      研究目的 川西南雷波安寨坪地区萤石矿赋存于下寒武统筇竹寺组碎屑岩内,成矿严格受区域近南北向峨边-金阳断裂带控制,矿体以脉状充填于构造裂隙中。该区萤石成矿过程尚缺乏有效约束,制约了对其矿床成因机制的认识和找矿勘查进程。
      研究方法 通过对典型萤石矿石中的萤石单矿物开展稀土元素地球化学、流体包裹体分析,探讨该区萤石矿流体性质、成矿过程及成矿模式。
      研究结果 区内萤石稀土元素总含量普遍较低,稀土元素配分模式呈略微右倾、中稀土元素富集的上凸型特征,普遍具较强的正Eu异常(δEu均值1.77)和弱的负Ce异常(δCe均值0.83),结合Tb/Ca−Tb/La及Y/Ho−La/Ho图解,认为研究区萤石矿为热液成因,矿床类型为热卤水型,且成矿环境是高氧逸度的开放体系。流体包裹体类型主要为富液相的气液两相包裹体,均一温度范围为81~209℃,盐度范围为2.1%~21.4%NaCleqv,反映成矿流体属中—低温、低盐度的NaCl−H2O体系。成矿热液流体与围岩发生水—岩反应主要是促使成矿元素F、Ca聚集,而萤石沉淀机制主要为深部卤水、大气降水发生流体混溶和流体降温冷却。
      结论 盆地热卤水及大气降水萃取地层中Ca、F等成矿元素后,使成矿元素在成矿热液中富集,构造和地层压力梯度致使热液沿断裂带向上运移至有利的容矿裂隙中,受细粒碎屑岩封闭盖层的遮挡,随成矿环境条件发生变化沉淀富集形成脉状萤石矿,成矿类型为中低温热液裂隙充填型萤石矿。本次研究为川西南地区萤石矿下一步的资源潜力评价及科学找矿工作提供了理论参考。

       

      Abstract:
      Objective The fluorite deposit exists in the clastic rocks of the Lower Cambrian Qiongzhusi Formation in the Anzhaiping area of Leibo County, southwest Sichuan Province. The mineralization of fluorite is controlled by the Ebian−Jinyang Fault, which is in the near north−south trend, and occurs in the structural fissure in the form of veins. The fluorite mineralization process in this area lacks effective constraints, hindering the understanding of its genetic mechanism and exploration progress.
      Methods This study investigates the fluid properties, mineralization process, and genetic model of the fluorite deposit through rare earth element (REE) geochemistry and fluid inclusion analysis of fluorite separates from typical ores.
      Results The fluorite exhibits generally low total REE concentrations, with REE patterns showing slight right inclination, middle REE enrichment, and convex shapes. Strong positive Eu anomalies (mean δEu=1.77) and weak negative Ce anomalies (mean δCe=0.83) are common. Combined with Tb/Ca–Tb/La and Y/Ho–La/Ho diagrams, the results indicate a hydrothermal origin for the fluorite mineralization, classifying the deposit as a brine−type formed in a high−oxygen fugacity open system. Fluid inclusions are predominantly liquid−rich two−phase types, with homogenization temperatures ranging from 81°C to 209°C and salinities from 2.1% to 21.4% NaCleqv, suggesting a medium–low temperature, low−salinity NaCl–H2O fluid system. Water–rock interaction between the ore−forming fluids and wall rocks primarily facilitated the enrichment of F and Ca, while fluorite precipitation was mainly triggered by fluid mixing between deep brine and meteoric water, accompanied by fluid cooling.
      Conclusions Basin−derived hot brines and meteoric water leached ore−forming elements such as Ca and F from the strata, enriching them in the hydrothermal fluid. Driven by tectonic forces and formation pressure gradients, the fluid migrated upward along the fault zone into favorable hosting fractures. Confined by fine−grained clastic rocks acting as a seal, changes in physicochemical conditions led to the precipitation and enrichment of fluorite, forming vein−type deposits classified as medium–low temperature hydrothermal fissure−filling fluorite ores. This study provides a theoretical basis for future resource potential assessment and scientific exploration of fluorite deposits in southwestern Sichuan.

       

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