南秦岭园门楼铜多金属矿床多相斑状岩脉成矿作用:锆石、石榴子石U–Pb定年及锆石微量元素的制约

    Mineralization associated with multiphase porphyritic dikes in the Yuanmenlou Cu−polymetallic deposit, South Qinling: Insights from U–Pb dating of zircon and garnet and zircon trace element geochemistry

    • 摘要:
      研究目的 园门楼矿床作为柞水−山阳矿集区内新发现的矽卡岩型铜多金属矿床,其成岩与成矿时代尚未明确,二者之间的成因关系亦不清楚,制约了对区域成矿规律的认识。
      研究方法 通过同位素年代学方法,精确厘定该矿床的成岩与成矿时代,揭示成岩-成矿作用的内在联系,并探讨其对区域找矿的指示意义。在矿床地质和岩相学特征研究的基础上,开展LA−ICP−MS锆石、石榴子石U−Pb定年及锆石微量元素分析,对数据进行综合对比研究。
      研究结果 园门楼矿区侵入岩呈小岩株状(受南北向断裂带与北西西向褶皱带交会部位控制)和岩脉状(受北西西向层间构造带控制)产出,岩性主要为花岗闪长斑岩、花岗斑岩及石英闪长玢岩。5件不同岩相岩脉样品获得锆石U−Pb年龄集中在147.2~148.0 Ma;矽卡岩中石榴子石获得U−Pb年龄为151.5±3.4 Ma。依据锆石稀土元素计算获得成矿岩浆氧逸度介于FMQ+0.49~FMQ+1.01之间,平均为FMQ+0.84(n=91),稀土元素显示正Ce异常(Ce/Ce*=152~251)、弱的负Eu异常(Eu/Eu*=0.66~0.76)及较高的(Ce/Nd)/Y值。
      结论 园门楼矿区不同岩相的斑状侵入岩均属于同一期次岩浆活动的产物,岩浆分异程度的差异及一定程度的围岩混染作用可能是导致岩相变化的主要原因;矿床成岩成矿时代为晚侏罗世,成矿岩浆属于中等氧化性富水岩浆,多相岩脉的侵入导致厚大矽卡岩带及多层铜矿体的形成。园门楼矿区岩脉相关的多层铜矿体的发现,进一步拓展了柞水−山阳矿集区的找矿空间,对找矿勘查部署具有重要参考意义。

       

      Abstract:
      Objective As a newly discovered skarn−type Cu−polymetallic deposit within the Zashui−Shanyang ore cluster, the Yuannenlou deposit lacks precise constraints on the timing of magmatism and mineralization, and the genetic relationship between these two processes remains unclear, which hinders a comprehensive understanding of regional metallogeny. This study employs isotopic geochronology to precisely determine the ages of magmatism and mineralization, elucidate their genetic linkage, and discuss the implications for regional ore prospecting.
      Methods Based on detailed investigations of deposit geology and petrographic characteristics, this study integrates LA–ICP–MS U–Pb dating of zircon and garnet with zircon trace element analysis. An integrated comparative analysis was conducted to constrain the petrogenesis and metallogeny of the deposit.
      Results The multiphase porphyritic intrusions in the Yuanmenlou deposit occur as small stocks (controlled by the intersection of N–S−trending fault zones and NWW–trending fold belts) and dikes (controlled by NWW−trending interlayered structural zones). The primary lithologies are granodiorite porphyry, granite porphyry, and quartz diorite porphyry. Zircon U–Pb dating of five dike samples yields ages ranging from 147.2 Ma to 148.0 Ma, while hydrothermal garnet from the skarn yields a U–Pb age of 151.5 ± 3.4 Ma. Zircon rare earth element (REE) compositions indicate high magmatic oxygen fugacity, with calculated oxygen fugacity values relative to the FMQ buffer ranging from +0.49 to +1.01 and averaging +0.84 (n=91). The zircons display strong positive Ce anomalies (Ce/Ce* = 152~251), weak negative Eu anomalies (Eu/Eu* = 0.68~0.76), and relatively high (Ce/Nd)/Y ratios.
      Conclusions The porphyritic intrusions with varying lithofacies in the Yuanmenlou area formed from a single magmatic system, with compositional variations attributed to magma differentiation and wall−rock assimilation. The timing of magmatism and mineralization is Late Jurassic. The ore−forming magma was moderately oxidized and hydrous. The emplacement of multiphase dikes was closely associated with the formation of thick skarn zones and multilayered copper orebodies. These findings expand the exploration potential of the Zhashui–Shanyang ore cluster and provide significant implications for future prospecting.

       

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