南秦岭园门楼铜多金属矿床多相斑状岩脉成矿作用:锆石、石榴子石U-Pb定年及锆石微量元素的制约

    Mineralization associated with multiphase porphyritic dikes in the Yuanmenlou Cu-polymetallic Deposit, South Qinling: insights from U–Pb dating of zircon and garnet and zircon trace element geochemistry

    • 摘要: 【研究目的】柞水—山阳矿集区是南秦岭造山带内重要的斑岩-矽卡岩型铜金多金属矿床分布区,但已有矿床多以中小型为主,找矿工作亟待突破。园门楼铜多金属矿床是近年矿集区内新发现并正在进行勘查的一处矽卡岩型铜多金属矿床,矿体主要产于多相斑状岩脉外接触带的厚大(垂向延伸超过500 m)矽卡岩带内。本文旨在进一步查明成岩成矿时代,揭示成岩与成矿之间的内在联系,并探讨其对区域成矿的指示。【研究方法】在详细矿床地质和岩相学特征研究的基础上,开展LA-ICP-MS锆石、石榴子石U-Pb定年及锆石微量元素的分析,对数据进行综合对比研究。【研究结果】园门楼矿区侵入岩呈小岩株状(受南北向断裂带与北西西向褶皱带交汇部位控制)和岩脉状(受北西西向层间构造带控制)产出,岩性主要为花岗闪长斑岩、花岗斑岩及石英闪长玢岩。5件不同岩相岩脉样品获得锆石U-Pb年龄集中在147.2~148.0 Ma;矽卡岩中石榴子石获得U−Pb年龄为151.5±3.4 Ma。依据锆石稀土元素计算获得成矿岩浆氧逸度介于FMQ+0.49~FMQ+1.01,平均为FMQ+0.84(n=91),稀土元素显示正的Ce异常(Ce/Ce*=152~251)、弱的负Eu异常(Eu/Eu*=0.66~0.76)及较高的(Ce/Nd)/Y比值。【结论】园门楼矿区不同岩相的斑状侵入岩均属于同一期次岩浆活动的产物,岩浆分异程度的差异及一定程度的围岩混染作用可能是导致岩相变化的主要原因;矿床成岩成矿时代为晚侏罗世,成矿岩浆属于中等氧化性富水岩浆,多相岩脉的侵入导致厚大矽卡岩带及多层铜矿体的形成。园门楼矿区岩脉相关的多层铜矿体的发现,进一步拓展了柞水—山阳矿集区的找矿空间,对找矿勘查部署具有重要参考意义。

       

      Abstract:  Objective The Zhashui-Shanyang ore-concentrated area is a key area within the South Qinling orogenic belt, known for its porphyry-skarn Cu-Au polymetallic deposits. However, most of the discovered deposits are of medium to small size, highlighting the urgent need for exploration breakthroughs. The Yuanmenlou Cu-polymetallic deposit, a newly discovered skarn-type deposit, is currently under exploration in this district. The ore body is mainly hosted within a thick (vertically extending over 500 meters) skarn zone, located at the exocontact of multiphase porphyritic dikes. This study aims to constrain the diagenetic and metallogenic ages, elucidate the genetic relationship between magmatism and mineralization, and discuss the implications for regional-scale mineralization. Methods Based on detailed studies of deposit geology and petrographic characteristics, LA–ICP–MS U–Pb dating of zircon and garnet, as well as trace element analysis of zircon, were carried out, and the results were subjected to an integrated comparative analysis. Results The multiphase porphyritic intrusions in the Yuanmenlou deposit occur as small stocks (controlled by the intersection of N–S-trending fault zones and NW–trending fold belts) and dikes (controlled by NW-trending interlayered structural zones). The main rock types are granodiorite porphyry, granite porphyry, and quartz diorite porphyrite. Zircon LA-ICP-MS U-Pb ages of five different dike samples range from 147.2~148.0 Ma, and the garnet from the skarn yielded a U–Pb age of 151.5 ± 3.4 Ma. Based on rare earth element (REE) compositions in zircon, the calculated magmatic oxygen fugacity values range from FMQ+0.49~FMQ+1.01, with an average of FMQ +0.84 (n=91). The REEs show strong positive Ce anomaly (Ce/Ce*=152~251), weak negative Eu anomaly (Eu/Eu*=0.68~0.76), and relatively high (Ce/Nd)/Y ratios. Conclusions The porphyritic intrusions with varying lithofacies in the Yuanmenlou area originated from a single magmatic event, with differences attributed to magma differentiation and wall-rock assimilation. The timing of diagenesis and mineralization is Late Jurassic, and the ore-forming magma was moderately oxidized and water-rich. Multiphase dike emplacement was closely associated with the formation of thick skarn zones and multilayered copper orebodies. These findings expand the exploration potential of the Zhashui–Shanyang ore cluster and offer valuable guidance for future prospecting.

       

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