东昆仑清水河东沟斑岩型钼矿床含矿岩体年龄、地球化学特征及其对成矿机制的约束

    Zircon U-Pb ages, geochemical characteristics and their constraints on metallogenic mechanism of ore-bearing porphyry in Qingshuihe Donggou molybdenum deposit, East Kunlun

    • 摘要:
      研究目的 清水河东沟斑岩型钼矿是东昆仑成矿带表性斑岩型矿床之一,详细厘定矿区斑岩体形成时代、成因和构造环境有助于提升东昆仑斑岩型钼矿床成矿规律认识。
      研究方法 对清水河东沟矿床与成矿关系密切的斑岩体开展了锆石U−Pb定年、岩石地球化学和锆石Hf同位素研究。
      研究结果 花岗闪长斑岩锆石U−Pb年龄为226.9±1.3 Ma(MSWD=1.03,n=18),闪长玢岩锆石U−Pb年龄为224.3±1.2 Ma(MSWD=0.47,n=15),限定矿床成矿年龄介于226.9~224.3 Ma之间。花岗闪长斑岩、闪长玢岩与花岗斑岩富硅、碱、铝,贫钛、镁,稀土元素含量中等,呈现轻稀土元素富集的右倾配分模式,前两者Eu亏损不明显(δEu=0.79~0.98),后者具有较明显的Eu亏损(δEu=0.22~0.24);均富集大离子亲石元素Rb、K、Ba等,亏损高场强元素Ta、Nb、Ti、P等,属准铝质—弱过铝质高钾钙碱性岩石系列。斑岩体锆石176Hf/177Hf值介于0.282510~0.282652之间,εHf(t)值介于−4.5~0.2之间,二阶段模式年龄介于1541~1240 Ma之间。
      结论 结合区域构造演化特征,认为清水河东沟斑岩体是晚三叠世后碰撞伸展环境下中元古界金水口岩群部分熔融的产物,并受到幔源物质的混染。

       

      Abstract:
      Objective The Qingshuihe Donggou porphyry molybdenum deposit is one of the representative porphyry deposits in the East Kunlun metallogenic belt.
      Methods Therefore, a detailed study of the age, genesis and tectonic environment of the porphyry intrusions in the Qingshuihe Donggou deposit is needed to improve the understanding of the metallogenic regularity of this area. In this paper, zircon U−Pb dating, petrogeochemistry and zircon Hf isotope of the porphyries from the Qingshuihe Donggou deposit, which are closely related to the Mo mineralization, have been studied.
      Results The zircon U−Pb age of granodiorite porphyry is 226.9 ± 1.3 Ma (MSWD = 1.03, n = 18), and the zircon U−Pb age of diorite porphyry is 224.3 ± 1.2 Ma (MSWD = 0.47, n = 15), These results indicate that this deposit formed at 226.9~224.3 Ma. Granodiorite porphyry, diorite porphyry and granite porphyry are rich in Si, Na, K and Al, poor in Ti and Mg, and show a right−leaning partition pattern characterized by the light rare earth element enrichment. The former two granites have no obvious Eu depletion (δEu: 0.79~0.98), whereas granite porphyry displays noticeable Eu depletion (δEu: 0.22~0.24). All of them are enriched in large ion lithophile elements (e.g., Rb, K, Ba), and depleted in high field strength elements (e.g., Ta, Nb, Ti, P), belonging to the metalluminous to weak peraluminous high K calc−alkaline granites. The 176Hf/177Hf ratio of zircon from these porphyry rocks ranges from 0.282510 to 0.282652, the εHf(t) value ranges from −4.5 to 0.2, and the two−stage model age ranges from 1541 Ma to 1240 Ma.
      Conclusions Based on the characteristics of regional tectonic evolution, it is deduced that these porphyries formed by partial melting of the Middle Proterozoic Jinshuikou Group under the Late Triassic post−collisional extension environment, and experienced magma mixing by mantle−derived materials.

       

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