含水矿物波速及其对俯冲带水含量的约束

    Sound velocities of hydrous minerals and its constraint on water content in subduction zones

    • 摘要:
      研究目的 含水矿物是将水从地球浅部运移至深部的重要载体,因此它们的物理化学性质对于理解地球内部的水循环至关重要。探讨不同含水矿物的弹性性质及影响因素,进而估算俯冲带的含水量。
      研究方法 系统介绍了近期高温高压下实验室波速测量方法,总结典型含水矿物弹性性质及各影响因素,比较了几种用于估算俯冲带物质组成和含水量的矿物模型。
      研究结果 研究发现,相较于地幔矿物,大部分低压含水矿物P波和S波速度普遍较低,而VP/VS值较高,这些性质与俯冲带地区的地球物理观测结果具有一致性;但一些高压含水矿物的波速与地幔矿物波速接近。含水矿物脱水前后波速的变化,可以用来揭示地球深部波速异常的原因。通过将含水矿物波速特征在地球深部环境下进行建模,并与地球物理观测数据进行比较,可以很好地解释俯冲带地区的速度异常,并有效约束其内部的含水量。
      结论 基于实验岩石学数据构建的波速—成分关系模型(如橄榄石—蛇纹石体系),结合蒙特卡洛模拟,实现了对俯冲带地幔楔蛇纹石化程度(10%~40%)和含水量(1%~5%)的定量估算。冷俯冲带(如日本东北、汤加)深部(200~400 km)的波速结构暗示其可能携带至少5%的水。

       

      Abstract:
      Objective Hydrous minerals are important carriers that transport water from the shallow to the deep of the Earth, so their physical and chemical properties are crucial to understanding the water cycle in the Earth's interior. This paper aims to explore the elastic properties of various hydrous minerals and their influencing factors, so as to constrain the estimation of water content in subduction zones.
      Methods The methods of measurement of wave velocity under high temperature and high pressure in laboratory are introduced, as well as the elastic properties and the effect of some factors on the elastic properties of typical hydrous minerals, and compares several mineral models used to estimate material composition and water content in subduction zones.
      Results It is found that the P and S wave velocities of low−pressure hydrous minerals are generally lower than those of mantle minerals, while the values of VP/VS are higher than those of mantle minerals. These properties are consistent with geophysical observations in subduction zones. However, the wave velocities of some high−pressure hydrous minerals are close to those of mantle minerals. The change of wave velocity of hydrous minerals before and after dehydration can be used to reveal the cause of abnormal wave velocity in deep Earth. By modeling hydrous minerals in the earth's deep environment and comparing with geophysical observation data, the water content and wave velocity anomalies in the subduction zone can be effectively constrained.
      Conclusions Based on velocity−minerals composition models constructed from experimental petrology data (e.g., olivine−serpentine system), combined with Monte Carlo simulation, the serpentization degree (approximately 10%~40%) and water content (about 1%~5%) of mantle wedge in subduction zones are quantitatively estimated. Seismic velocity structures at depths of 200~400 km in cold subduction zones such as Northeast Japan and Tonga suggest water content in these regions are at least 5%.

       

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